SnO2/石墨烯复合薄膜的合成、表征及乙醇气敏性能

M. Jayaweera, R.C.L. De Silva, I. Kottegoda, S. Rosa
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引用次数: 11

摘要

采用一种新型的一步原位声化学方法,制备了由二氧化硅/氮化镓纳米复合材料组成的高性能传感器。利用SnCl - 2的还原性对氧化石墨烯(GO)进行还原,使SnCl - 2在石墨烯基面上转化为sno2。通过x射线衍射(XRD)、扫描电镜(SEM)和傅里叶变换红外光谱(FTIR)的综合表征表明,SnO 2 /Gn复合材料的合成成功。该气体传感器的电流-电压(I-V)特性具有理想的欧姆特性和低电阻。为了验证该产品在传感方面的应用,采用sno2 /Gn复合材料制作了气体传感器,并将其用于室温(27℃)下的乙醇蒸汽检测。结果表明,在150 ppm乙醇蒸汽条件下,sno2 /Gn复合材料具有较高的传感性能,响应速度快,重现性好,达到17.54%。此外,在正常工作条件下,基于sno2 /Gn的气体传感器的性能在很长一段时间内都非常稳定。因此,sno2 /Gn可以被认为是一种优秀的传感材料,在传感器上也有更广泛的应用潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis, characterization and ethanol vapor sensing performance of SnO2/Graphene composite film
High performing sensor consisting of SnO 2 /Gn nanocomposite was fabricated using a novel one-step in-situ sonochemical method. The reducing properties of SnCl 2 was used to reduce graphite oxide (GO) so that SnCl 2 could be transformed to SnO 2 on the basal plane of graphene. The combined characterizations including X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier Transformed Infra-Red spectroscopic data (FTIR) indicated the successful formation of SnO 2 /Gn composites. Current-voltage (I-V) characteristics of the gas sensor showed ideal ohmic behavior having low resistance. To demonstrate the product on sensing application, gas sensors were fabricated using SnO 2 /Gn composites and used in detecting ethanol vapor at room temperature (27°C).The results indicate that the SnO 2 /Gn composite exhibits a considerably high sensing performance of 17.54% response at 150 ppm ethanol vapor, rapid response and reproducibility. Furthermore, the performance of the gas sensor based on SnO 2 /Gn is very stable for a long period of time under normal operating conditions. Therefore, it is suggested that SnO 2 /Gn can be considered as an excellent sensing material which also has a potential for wider range of applications on sensors.
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