{"title":"硅烷偶联剂对硅胶和蒙脱土的功能化研究，四。固定化催化剂在有机化合物双氧氧化中的应用","authors":"Yasuhiko Kurusu","doi":"10.1016/0923-1137(95)00020-J","DOIUrl":null,"url":null,"abstract":"<div><p>Immobilized catalysts were prepared from silica gel and montmorillonite functionalized by silane coupling reagents. Complexes with metal ions were easily formed. The dioxygen oxidation of hydrocarbon using the immobilized catalyst was investigated. Cyclohexanol (mainly) and some cyclohexanone were produced by the oxidation of cyclohexane at ordinary temperature, under atmospheric pressure. Dioxygen oxidation of the non-activated β-position of the ethyl group in ethylbenzene was observed in the presence of cobalt ion-immobilized montmorillonite catalyst in the presence of lithium ion.</p></div>","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":"25 1","pages":"Pages 63-68"},"PeriodicalIF":0.0000,"publicationDate":"1995-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-1137(95)00020-J","citationCount":"10","resultStr":"{\"title\":\"Functionalization of silica gel and montmorillonite by silane coupling reagent, IV. Application as immobilized catalysts in dioxygen oxidation of organic compounds\",\"authors\":\"Yasuhiko Kurusu\",\"doi\":\"10.1016/0923-1137(95)00020-J\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Immobilized catalysts were prepared from silica gel and montmorillonite functionalized by silane coupling reagents. Complexes with metal ions were easily formed. The dioxygen oxidation of hydrocarbon using the immobilized catalyst was investigated. Cyclohexanol (mainly) and some cyclohexanone were produced by the oxidation of cyclohexane at ordinary temperature, under atmospheric pressure. Dioxygen oxidation of the non-activated β-position of the ethyl group in ethylbenzene was observed in the presence of cobalt ion-immobilized montmorillonite catalyst in the presence of lithium ion.</p></div>\",\"PeriodicalId\":20864,\"journal\":{\"name\":\"Reactive Polymers\",\"volume\":\"25 1\",\"pages\":\"Pages 63-68\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0923-1137(95)00020-J\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reactive Polymers\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/092311379500020J\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reactive Polymers","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/092311379500020J","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Functionalization of silica gel and montmorillonite by silane coupling reagent, IV. Application as immobilized catalysts in dioxygen oxidation of organic compounds
Immobilized catalysts were prepared from silica gel and montmorillonite functionalized by silane coupling reagents. Complexes with metal ions were easily formed. The dioxygen oxidation of hydrocarbon using the immobilized catalyst was investigated. Cyclohexanol (mainly) and some cyclohexanone were produced by the oxidation of cyclohexane at ordinary temperature, under atmospheric pressure. Dioxygen oxidation of the non-activated β-position of the ethyl group in ethylbenzene was observed in the presence of cobalt ion-immobilized montmorillonite catalyst in the presence of lithium ion.
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