一种测定汽油机气体组分混合辛烷值的新方法

E. B. Kovaleva, S. G. Dyachkova, A. Ganina, I. Kuzora, V. A. Sergeev
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引用次数: 0

摘要

气态组分(GC)的辛烷值目前是使用从碳氢化合物组成出发的计算方法确定的。该方法仅提供了研究辛烷值(RON)的测定。由此确定的辛烷值的实际值与预测值之间的差异导致对这些成分引入燃料的估计过高,从而导致燃料性能和生产的经济指标降低。因此,开发一种测定低沸点组分共混辛烷值的新方法,对于设计最佳的车用燃料配方具有极其重要的意义。一种测定汽油机气体组分混合辛烷值(RON和MON)的方法得到了改进,这是由于采用鼓泡法进行初步样品制备,该方法考虑了C4烃和戊烯组分的比例以及基础燃料组分的化学性质。结果表明,气体组分的共混辛烷值取决于基组分的碳氢化合物组成。应用所开发的方法来确定发动机燃料的气态组分的辛烷值,使我们能够在低沸点副产品的参与下获得汽油的最佳配方,并提高了预测燃料成分的准确性,从而提高了生产的经济性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A new approach to determining the blending octane number of gaseous components of motor gasolines
The octane number for gaseous components (GC) is currently determined using the calculation method proceeding from the hydrocarbon composition. The method provides determination of the research octane number (RON) only. A discrepancy between the actual and predicted values of the octane number thus determined leads to an overestimated introduction of these components into the fuel which results in the reduced fuel performance and economic indicators of the production. In this regard, the development of a new approach to the determination of the blending octane number of low-boiling components is extremely important for designing optimal formulations of motor fuels. A method for determining the blending octane numbers (both RON and MON) of motor gasoline gaseous components has been improved due to preliminary sample preparation by bubbling which provided taking into account the proportion of involving fractions of C4 hydrocarbon and pentane-amylene along with the chemical nature of the base fuel components. It is shown that the value of the blending octane number for gaseous components depends on the hydrocarbon composition of the base component. Application of the developed method to determining the blending octane number of gaseous components of motor fuels allowed us to obtain optimal formulations of gasoline with the involvement of low-boiling by-products and increased the accuracy of forecasting the composition of fuels thus improving the economic performance of the production.
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