Andreas Hirsch主编:富勒烯和相关结构,施普林格出版社,柏林-海德堡,1999

Z. Slanina
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引用次数: 1

摘要

这本书是一个新的和新鲜的富勒烯化学贡献卷,由六个单独的章节。这些章节致力于从富勒烯有机化学和材料科学中选择有吸引力的主题。该卷主要涉及富勒烯衍生物,而不是原始富勒烯。这本书以a .赫希写的关于富勒烯反应原理的一章开篇。本章调查目前的知识和反应原理与几何和电子性质。这些原理可归纳为六种反应性规则(锥体化、电负性、键交替、加成物区域化学、高加合物、惰性凹表面化学法拉第笼)。鲁宾讨论了富勒烯的开环反应和设计方法的内嵌金属配合物。他认为开环反应实际上有可能为大规模地(包括那些含有过渡金属的)获得内嵌甲基富勒烯提供方便。虽然为了形成广泛开放的孔口,仍有几个问题需要解决,但它们似乎不是不可克服的。本文综述了杂富勒烯化学的最新进展,作者包括j.c. Hummelen、c.b allavia - lund和f.w udl。他们特别讨论了氮杂富勒烯- aza[60]富勒烯和aza ' i;O]富勒烯及其衍生物的合成路线。对氮杂烯的理化性质也作了介绍
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Andreas Hirsch, Ed.: Fullerenes and Related Structures Springer-Verlag, Berlin — Heidelberg, 1999
The book is a new and fresh contributed volume on fullerene chemistry, consisting of six individual chapters. The chapters are devoted to selected attractive topics from fullerene organic chemistry and materials science. The volume deals primarily with fullerene derivatives rather than with pristine fullerenes. The book opens with a chapter on principles of fullerene reactivity written by A. Hirsch. The chapter surveys present knowledge and reactivity principles linked to the geometric and electronic properties. The principles are summarized into six reactivity rules (pyramidalization, electronegativity, bond alternation, regiochemistry of additions, higher adducts, inert concave surface chemical Faraday cage). Y. Rubin discusses ring opening reactions of fullerenes and designed approaches to endohedral metal complexes. He argues that ring opening reactions actually have the potential to provide easy access to endohedral metttllofullerenes on a large scale (including those with transition metals). Although several problems still have to be addressed in order to form widely open orifices, they do not seem insurmountable. The state of the art in heterofullerene chemistry is reviewed by J. C. Hummelen, C. Bellavia-Lund and F. Wudl. They in particular deal with azafullerenes the synthetic routes towards aza[60]fullerene and aza"i;O]fullerene and their derivatives. Physicochemical properties of azafullerenes are also
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