亚砷酸钠和乙酸砷钠对氰化镀铜液性能影响的比较

G.W. Marshall, J. Green, P. Leggett
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引用次数: 0

摘要

研究了添加1 × 10-2 mM亚砷酸钠和乙酸亚砷钠对黄铜镀液的影响。结果表明,乙酸砷是一种比亚砷酸盐更好的增白剂。电位-电流密度曲线研究表明,砷化物降低了阴极极化,而乙酸砷则增加了阴极极化。这两种添加剂都改变了沉积黄铜的结构,提高了其硬度。添加砷乙酸钠后得到的镀层颜色随镀层厚度变化很大。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A comparison of the effects of sodium arsenite and sodium arsenoacetate upon the behaviour of a cyanide brass plating solution

The effects of 1 X 10-2 mM additions of sodium arsenite and sodium arsenoacetate upon a brass plating solution have been studied. The arsenoacetate was found to be a better brightening agent than the arsenite.

Potential-current density curve studies showed that the arsenide decreased cathodic polarisation but that the arsenoacetate increased polarisation. Both additions led to modifications of the structure of the deposited brass and to increases in its hardness. The colour of deposits obtained using sodium arsenoacetate additions varied considerably with deposit thickness.

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