椰壳颗粒增强聚琥珀酸丁烯和聚琥珀酸丁烯-聚己内酯基复合材料的性能

IF 2.1 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES
S. Savetlana, T. Gough, A. Kelly
{"title":"椰壳颗粒增强聚琥珀酸丁烯和聚琥珀酸丁烯-聚己内酯基复合材料的性能","authors":"S. Savetlana, T. Gough, A. Kelly","doi":"10.1080/09276440.2023.2190680","DOIUrl":null,"url":null,"abstract":"ABSTRACT In order to increase the interfacial adhesion between polybutylene succinate and coconut shell particles, two kinds of chemical treatment of coconut shell particle were carried out. Firstly, a 5% sodium hydroxide treatment and secondly, a 2% sodium hydroxide plus silane coupling agent treatment. The possibility of increasing matrix adhesion has also been explored through addition of polycaprolactone to polybutylene succinate as a matrix. Composites were produced using extrusion prior to injection moulding. The results show that, compared with neat polybutylene succinate, composites with low percentage of particle loading have a higher tensile strength and strain at break despite their lower elastic modulus. A higher elastic modulus can be obtained for composites with higher particle loadings through sacrifice of their ductility. The same trend is observed for composites with the polymer-blend matrix. Scanning electron micrographs show good adhesion between particle and matrix for particles that undergo the second treatment. At low percentage of particle addition, the crystallinity of the composites is higher than the neat polybutylene succinate, however melting temperature is less affected by the addition of reinforcement. Rheological properties such as storage modulus, loss modulus and complex viscosity of the composites are higher than for neat polybutylene succinate. GRAPHICAL ABSTRACT","PeriodicalId":10653,"journal":{"name":"Composite Interfaces","volume":"25 1","pages":"1119 - 1144"},"PeriodicalIF":2.1000,"publicationDate":"2023-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Properties of polybutylene succinate and polybutylene succinate -polycaprolactone based composite reinforced with coconut shell particles\",\"authors\":\"S. Savetlana, T. Gough, A. Kelly\",\"doi\":\"10.1080/09276440.2023.2190680\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT In order to increase the interfacial adhesion between polybutylene succinate and coconut shell particles, two kinds of chemical treatment of coconut shell particle were carried out. Firstly, a 5% sodium hydroxide treatment and secondly, a 2% sodium hydroxide plus silane coupling agent treatment. The possibility of increasing matrix adhesion has also been explored through addition of polycaprolactone to polybutylene succinate as a matrix. Composites were produced using extrusion prior to injection moulding. The results show that, compared with neat polybutylene succinate, composites with low percentage of particle loading have a higher tensile strength and strain at break despite their lower elastic modulus. A higher elastic modulus can be obtained for composites with higher particle loadings through sacrifice of their ductility. The same trend is observed for composites with the polymer-blend matrix. Scanning electron micrographs show good adhesion between particle and matrix for particles that undergo the second treatment. At low percentage of particle addition, the crystallinity of the composites is higher than the neat polybutylene succinate, however melting temperature is less affected by the addition of reinforcement. Rheological properties such as storage modulus, loss modulus and complex viscosity of the composites are higher than for neat polybutylene succinate. GRAPHICAL ABSTRACT\",\"PeriodicalId\":10653,\"journal\":{\"name\":\"Composite Interfaces\",\"volume\":\"25 1\",\"pages\":\"1119 - 1144\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2023-03-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Composite Interfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1080/09276440.2023.2190680\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composite Interfaces","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/09276440.2023.2190680","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
引用次数: 0

摘要

摘要为了提高聚丁二酸丁二烯与椰壳颗粒之间的界面附着力,对椰壳颗粒进行了两种化学处理。首先,5%氢氧化钠处理,其次,2%氢氧化钠加硅烷偶联剂处理。通过将聚己内酯添加到聚丁二酸丁二酯中作为基质,还探讨了增加基质粘附性的可能性。复合材料是在注塑成型之前用挤压法生产的。结果表明:与纯聚琥珀酸丁二烯相比,低颗粒加载比例的复合材料具有更高的拉伸强度和断裂应变,但弹性模量较低;高颗粒载荷的复合材料可以通过牺牲其延性来获得较高的弹性模量。聚合物共混基体的复合材料也有同样的趋势。扫描电镜显示,二次处理后的颗粒与基体之间具有良好的附着力。当颗粒添加量较少时,复合材料的结晶度比纯丁二酸聚丁二烯高,但增强剂的加入对熔融温度的影响较小。该复合材料的存储模量、损失模量和复合粘度等流变性能均高于纯聚琥珀酸丁二烯。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Properties of polybutylene succinate and polybutylene succinate -polycaprolactone based composite reinforced with coconut shell particles
ABSTRACT In order to increase the interfacial adhesion between polybutylene succinate and coconut shell particles, two kinds of chemical treatment of coconut shell particle were carried out. Firstly, a 5% sodium hydroxide treatment and secondly, a 2% sodium hydroxide plus silane coupling agent treatment. The possibility of increasing matrix adhesion has also been explored through addition of polycaprolactone to polybutylene succinate as a matrix. Composites were produced using extrusion prior to injection moulding. The results show that, compared with neat polybutylene succinate, composites with low percentage of particle loading have a higher tensile strength and strain at break despite their lower elastic modulus. A higher elastic modulus can be obtained for composites with higher particle loadings through sacrifice of their ductility. The same trend is observed for composites with the polymer-blend matrix. Scanning electron micrographs show good adhesion between particle and matrix for particles that undergo the second treatment. At low percentage of particle addition, the crystallinity of the composites is higher than the neat polybutylene succinate, however melting temperature is less affected by the addition of reinforcement. Rheological properties such as storage modulus, loss modulus and complex viscosity of the composites are higher than for neat polybutylene succinate. GRAPHICAL ABSTRACT
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Composite Interfaces
Composite Interfaces 工程技术-材料科学:复合
CiteScore
5.00
自引率
3.80%
发文量
58
审稿时长
3 months
期刊介绍: Composite Interfaces publishes interdisciplinary scientific and engineering research articles on composite interfaces/interphases and their related phenomena. Presenting new concepts for the fundamental understanding of composite interface study, the journal balances interest in chemistry, physical properties, mechanical properties, molecular structures, characterization techniques and theories. Composite Interfaces covers a wide range of topics including - but not restricted to: -surface treatment of reinforcing fibers and fillers- effect of interface structure on mechanical properties, physical properties, curing and rheology- coupling agents- synthesis of matrices designed to promote adhesion- molecular and atomic characterization of interfaces- interfacial morphology- dynamic mechanical study of interphases- interfacial compatibilization- adsorption- tribology- composites with organic, inorganic and metallic materials- composites applied to aerospace, automotive, appliances, electronics, construction, marine, optical and biomedical fields
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信