1.2.4. 基于长跨度壬二酸和4,4′-联吡啶配体的Ni(aze)(4,4′-bipy)(H2O)的合成、晶体结构和热稳定性

Communications in Inorganic Synthesis Pub Date : 1900-01-01 DOI:10.21060/CIS.V1I2.2000

G. Song, F. Bai, Yan Xie, Y. Xing

{"title":"1.2.4. 基于长跨度壬二酸和4,4′-联吡啶配体的Ni(aze)(4,4′-bipy)(H2O)的合成、晶体结构和热稳定性","authors":"G. Song, F. Bai, Yan Xie, Y. Xing","doi":"10.21060/CIS.V1I2.2000","DOIUrl":null,"url":null,"abstract":"Abstract: One new three-dimensional (3D) supramolecular longer-spanning azelaic acid (H 2 aze) complex: Ni(aze)(4,4 ′ – bipy)(H 2 O) (4,4 ′ -bipy = 4,4 ′ -bipyridine) has been synthesized using hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, UV spectrum, powder X-ray diffraction, TG analysis and single crystal X–ray diffraction. Structural analysis reveals that the title complex is six-coordinate and connected by the azelaic acid and 4,4 ′ -bipy ligands to generate a 2D planar structure, further linked through the interaction of hydrogen bond of C–H···O to form a 3D supramolecular structure . Supporting information: FT-IR, UV-Vis, X-Ray, Cif file","PeriodicalId":10648,"journal":{"name":"Communications in Inorganic Synthesis","volume":"1 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"1.2.4. Synthesis, crystal structure and thermal stability property of Ni(aze)(4,4′ –bipy)(H2O) based on longer-spanning azelaic acid and 4,4′ -bipyridine ligands\",\"authors\":\"G. Song, F. Bai, Yan Xie, Y. Xing\",\"doi\":\"10.21060/CIS.V1I2.2000\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract: One new three-dimensional (3D) supramolecular longer-spanning azelaic acid (H 2 aze) complex: Ni(aze)(4,4 ′ – bipy)(H 2 O) (4,4 ′ -bipy = 4,4 ′ -bipyridine) has been synthesized using hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, UV spectrum, powder X-ray diffraction, TG analysis and single crystal X–ray diffraction. Structural analysis reveals that the title complex is six-coordinate and connected by the azelaic acid and 4,4 ′ -bipy ligands to generate a 2D planar structure, further linked through the interaction of hydrogen bond of C–H···O to form a 3D supramolecular structure . Supporting information: FT-IR, UV-Vis, X-Ray, Cif file\",\"PeriodicalId\":10648,\"journal\":{\"name\":\"Communications in Inorganic Synthesis\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Communications in Inorganic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21060/CIS.V1I2.2000\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Communications in Inorganic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21060/CIS.V1I2.2000","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

摘要:利用水热合成了一种新的三维(3D)超分子长跨越壬二酸(h2 aze)配合物:Ni(aze)(4,4 ' -bipy)(h2o)(4,4 ' -bipy = 4,4 ' -联吡啶)，并通过元素分析、红外光谱、紫外光谱、粉末x射线衍射、热重分析和单晶x射线衍射对其进行了表征。结构分析表明，标题配合物为六坐标结构，由壬二酸和4,4 ' -bipy配体连接形成二维平面结构，再通过C-H··O氢键相互作用连接形成三维超分子结构。支持信息:FT-IR, UV-Vis, X-Ray, Cif文件

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

1.2.4. Synthesis, crystal structure and thermal stability property of Ni(aze)(4,4′ –bipy)(H2O) based on longer-spanning azelaic acid and 4,4′ -bipyridine ligands

Abstract: One new three-dimensional (3D) supramolecular longer-spanning azelaic acid (H 2 aze) complex: Ni(aze)(4,4 ′ – bipy)(H 2 O) (4,4 ′ -bipy = 4,4 ′ -bipyridine) has been synthesized using hydrothermal conditions and characterized by elemental analysis, IR spectroscopy, UV spectrum, powder X-ray diffraction, TG analysis and single crystal X–ray diffraction. Structural analysis reveals that the title complex is six-coordinate and connected by the azelaic acid and 4,4 ′ -bipy ligands to generate a 2D planar structure, further linked through the interaction of hydrogen bond of C–H···O to form a 3D supramolecular structure . Supporting information: FT-IR, UV-Vis, X-Ray, Cif file

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Communications in Inorganic Synthesis

自引率

0.00%

发文量