增强材料对MWCNT填充热塑性复合材料拉伸性能的影响

Shrinatha R. Katti
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摘要

聚丙烯(PP)是应用最广泛的工程聚合物之一。本研究采用双螺杆挤出法将多壁碳纳米管(MWCNT)熔融共混到PP中,并对两组不同配比的复合材料进行了研究。第一组使用了2.5%、5%和10%的MWCNT,而另一组使用了1.25、3.75%和7.5%的MWCNT。然后使用50吨机器注塑成型,根据ASTM标准生产PP+MWCNT复合材料最平整的样品,并用于进行拉伸试验。虽然破坏应变大幅降低,极限抗拉强度略有增加,但MWCNT加固后的杨氏模量增加了近65%。这些实验值与随机取向纤维的Halpin-Tsai模型计算的理论值进行了比较。理论数据与实验数据有很大的偏差。本文对理论和实验结果进行了比较和分析。对两组复合材料的杨氏模量变化均建立了适合的数学模型方程。已经发现,就方程的参数而言,变化是恒定的。这表明拉伸性能的变化与增强程度成正比。关键词:聚丙烯,碳纳米管,双螺杆挤出机,纳米复合材料,Halpin-Tsai
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Reinforcement on Tensile Behavior of MWCNT Filled Thermoplastic Composites
Polypropylene (PP) is one of the most widely used engineering polymers. In this study, multiwalled carbon nanotube (MWCNT) has been melt blended into PP using twin screw extrusion process, indifferent ratios for two different set of composites. For first set, 2.5, 5 and 10 wt.%of MWCNT was used whereas for another set 1.25, 3.75 and 7.5% were the values. The extruded pellets were then injection moulded using a 50 Ton machine to produce PP+MWCNT composite flattest specimens according to ASTM standards and were used to carry out the tensile tests. While there is a huge reduction in failure strain and a marginal increase in ultimate tensile strength, there was nearly 65 % increase in young’s modulus with MWCNT as reinforcement. These experimental values were compared with the theoretical values calculated using Halpin-Tsai model for randomly oriented fibres.There was significant deviationof the theoretical data from the experimental data. The comparison and analysis of theoretical and experimental results are carried out in the present work. A mathematical model equation has been fit for the variation of young’s modulus in both the sets of composites. The variation has been found to be constant in terms of the parameters of the equation. This shows the variation of the tensile properties are proportional to the degree of reinforcement. Keywords—Polypropylene, carbon-nanotubes, twin-screw extruder, nano-composites, Halpin-Tsai.
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