冷分子碰撞中重叠共振的立体动力学控制

M. Morita, Q. Yao, Changjian Xie, Hua Guo, N. Balakrishnan
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引用次数: 7

摘要

共振分子碰撞的立体动力学控制已成为冷分子研究的一个新前沿。最近的实验研究主要集中在弱相互作用的分子系统上,如与H$_2$, D$_2$和He的HD碰撞。本文报道了这种控制在HCl和H$_2$冷碰撞中发生旋转弛豫的强相互作用系统中的可能性。使用全六维的显式量子散射计算表明,即使在狭窄的能量范围内共存多个(重叠的)形状共振,也可以对碰撞动力学进行鲁棒控制,这表明冷立体化学为超越简单系统的许多分子提供了巨大的希望。我们展示了一个引人注目的情况下,重叠共振的两个突出的峰同时被HCl分子的适当排列关闭。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Stereodynamic control of overlapping resonances in cold molecular collisions
Stereodynamic control of resonant molecular collisions has emerged as a new frontier in cold molecule research. Recent experimental studies have focused on weakly interacting molecular systems such as HD collisions with H$_2$, D$_2$ and He. We report here the possibility of such control in strongly interacting systems taking rotational relaxation in cold collisions of HCl and H$_2$. Using explicit quantum scattering calculations in full six dimensions it is shown that robust control of the collision dynamics is possible even when multiple (overlapping) shape-resonances coexist in a narrow energy range, indicating that cold stereochemistry offers great promise for many molecules beyond simple systems. We demonstrate a striking case where two prominent peaks in overlapping resonances are switched-off simultaneously by suitable alignment of the HCl molecule.
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