Prediction of water retention properties of Syrian clayey soils

Abstract Studies on clayey soils developed in temperate areas have shown that their water retention properties are related to both the clay content and the specific pore volume of the clay, the latter being related to the hydric history of the soil, that is to the drying/wetting cycles. Our objective was to discuss the validity of these results for clayey soils developed in semi-arid areas. Samples were collected in soils located in Syria. Physico-chemical properties were determined. Water content was measured at field capacity and for water potentials ranging from −10 to −15,000 hPa. X-ray diffraction analyses were performed on the clay fraction to identify the clay. Results showed that the clays have both a high cation exchange capacity (0.707–0.891 mmol+ g−1 of clay) and a high external specific surface area (112 and 178 m2 g−1 of clay). These values are consistent with the X-ray diffraction results which showed the presence of a high proportion of smectite in most horizons and secondarily of varying proportions of illite and chlorite; kaolinite, while present, was not abundant. Results also showed that the amount of water retained by the clay according to the water potential was closely related to the specific pore volume of the clay at field capacity. Regression equations established by using both the data published earlier and those of this study enabled us to predict the water retention properties of clayey soils for a larger range of clay mineralogy and climatic environments including semi-arid environments than previously discussed in the literature.