{"title":"1.3.3. 新型钌多吡啶配合物[Ru(phen)2(4,4′-二羧基-2,2′-联吡啶)]PF6的合成、表征及晶体结构","authors":"Jiaxi Chen, Jing Sun, Jufang Kong, Wen-Xiu Chen, Hongqing Hao","doi":"10.21060/CIS.V1I3.2013","DOIUrl":null,"url":null,"abstract":"Abstract: A new Ru(II) polypyridyl complex, [Ru(phen)2(4,4'-dicarboxy-2,2'-bipyridine)]PF6·1.5H2O, was synthesized andcharacterized by single crystal X-ray diffraction, elementalanalyses, electrospray ionization mass spectrometry, infraredspectra, ultraviolet (UV) spectra, and emission spectra. Thestructure of the cation [Ru(phen)2(4,4'-(COO-),(COOH)-2,2'-bpy)]+ consists of a six-coordinated ruthenium atom chelated bytwo phen ligands and one 4,4'-dicarboxy-2,2'-bipyridine ligand.The absorption spectrum of the Ru(II) complex is characterizedby two intense ligand-centered transitions in the UV region andone metal to ligand charge transfer in the visible region. Moreover,the complex can display luminescence in water at roomtemperature, with maximum emission at 623 nm.Supporting information: Cif file","PeriodicalId":10648,"journal":{"name":"Communications in Inorganic Synthesis","volume":"20 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"1.3.3. Synthesis, characterization and crystal structure of a new ruthenium polypyridyl complex [Ru(phen)2(4,4'-dicarboxy-2,2'- bipyridine)]PF6\",\"authors\":\"Jiaxi Chen, Jing Sun, Jufang Kong, Wen-Xiu Chen, Hongqing Hao\",\"doi\":\"10.21060/CIS.V1I3.2013\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract: A new Ru(II) polypyridyl complex, [Ru(phen)2(4,4'-dicarboxy-2,2'-bipyridine)]PF6·1.5H2O, was synthesized andcharacterized by single crystal X-ray diffraction, elementalanalyses, electrospray ionization mass spectrometry, infraredspectra, ultraviolet (UV) spectra, and emission spectra. Thestructure of the cation [Ru(phen)2(4,4'-(COO-),(COOH)-2,2'-bpy)]+ consists of a six-coordinated ruthenium atom chelated bytwo phen ligands and one 4,4'-dicarboxy-2,2'-bipyridine ligand.The absorption spectrum of the Ru(II) complex is characterizedby two intense ligand-centered transitions in the UV region andone metal to ligand charge transfer in the visible region. Moreover,the complex can display luminescence in water at roomtemperature, with maximum emission at 623 nm.Supporting information: Cif file\",\"PeriodicalId\":10648,\"journal\":{\"name\":\"Communications in Inorganic Synthesis\",\"volume\":\"20 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2013-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Communications in Inorganic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21060/CIS.V1I3.2013\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Communications in Inorganic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21060/CIS.V1I3.2013","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
1.3.3. Synthesis, characterization and crystal structure of a new ruthenium polypyridyl complex [Ru(phen)2(4,4'-dicarboxy-2,2'- bipyridine)]PF6
Abstract: A new Ru(II) polypyridyl complex, [Ru(phen)2(4,4'-dicarboxy-2,2'-bipyridine)]PF6·1.5H2O, was synthesized andcharacterized by single crystal X-ray diffraction, elementalanalyses, electrospray ionization mass spectrometry, infraredspectra, ultraviolet (UV) spectra, and emission spectra. Thestructure of the cation [Ru(phen)2(4,4'-(COO-),(COOH)-2,2'-bpy)]+ consists of a six-coordinated ruthenium atom chelated bytwo phen ligands and one 4,4'-dicarboxy-2,2'-bipyridine ligand.The absorption spectrum of the Ru(II) complex is characterizedby two intense ligand-centered transitions in the UV region andone metal to ligand charge transfer in the visible region. Moreover,the complex can display luminescence in water at roomtemperature, with maximum emission at 623 nm.Supporting information: Cif file
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