研究与应用于光合作用作用的蓝色反应性160电极和应用

Thamrin Azis, Maulidiyah Maulidiyah, Muhammad Nurdin, Muhammad Zakir Muzakkar, Ratna, L. A. Kadir, Viesta Valentin Octavian, T. Nurwahida, C. Bijang, Haris W
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摘要

采用阳极氧化法制备二氧化钛(TiO2)电极,并采用浸涂技术涂覆钛铁矿(FeTiO3)。研制了钛铁矿(FeTiO3)包覆TiO2/Ti板电极,用于紫外和可见光光催化降解活性蓝160染料。FeTiO3-TiO2 / Ti复合材料在紫外照射下降解活性蓝160,与TiO2相比具有可见光催化作用。结果XRD表征TiO2晶体在2θ,即35.1°(110)处以锐钛矿形式存在,Fe掺杂剂在TiO2上以锐钛矿和金红石形式取代。FTIR数据表明,在波数<700 nm处存在Fe-O键。SEM-EDX结果表明,涂层表面形成了一层薄薄的FeTiO3,表明浸镀方法在涂层过程中是有效的。在可见光下,FeTiO3-TiO2 /Ti电极的抗氧化活性比TiO2/Ti电极高。光催化降解0.5 ppm浓度的活性蓝160染料的结果表明,TiO2/Ti和FeTiO3-TiO2/Ti电极在可见光下具有活性,降解率常数分别为48%和69%。关键词:电极,钛铁矿,TiO2 / Ti,降解,活性蓝160,光电催化
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Studi dan Aplikasi Elektroda FeTiO3-TiO2/Ti untuk Degradasi Reactive Blue 160 dengan Metode Fotoelektrokatalisis
The manufacture of titanium dioxide (TiO2) electrodes is made by anodizing method and coated with ilmenite (FeTiO3) through a dip-coating technique. The ilmenite (FeTiO3) coated TiO2/Ti plate electrode was developed for the degradation of the reactive blue 160 dye under photoelectrocatalytic UV and Visible light irradiation. The performance of FeTiO3-TiO2 / Ti composites degrades reactive blue 160 under UV irradiation and is visible photoelectrocatalytically compared to TiO2. The results of XRD characterization of TiO2 crystals in the form of anatase at 2θ, namely 35.1 ° (110), and the substitution of Fe dopant on TiO2 in the form of anatase and rutile crystals. FTIR data indicated the presence of Fe-O bonds at wave numbers <700 nm. SEM-EDX results showed a thin layer of FeTiO3 was formed, indicating that the dip-coating method was effective in the coating process. The performance of the FeTiO3-TiO2 / Ti electrode has the highest activity against the oxidation process under visible light than the TiO2/Ti electrode. The results of degradation of reactive blue 160 dye with a concentration of 0.5 ppm by photoelectrocatalytic showed that the TiO2 / Ti and FeTiO3-TiO2/Ti electrodes were active in visible irradiation with degradation rate constants of 48% and 69%. Keywords: Electrodes, ilmenite, TiO2 / Ti, degradation, reactive blue 160, photoelectrocatalysis
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