具有竞争放热和吸热反应的一维混沌层流

S. Watt, Zhejun Huang, H. Sidhu, A. McIntosh, J. Brindley
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引用次数: 0

摘要

摘要考虑了混沌平流条件下竞争放热和吸热反应的数值解。结果行为的特点是强烈依赖于竞争反应历史。燃烧温度与简单的焓计算没有直接联系,因此主要参数之间的相互作用是微妙的,特别是Damköhler数字,放热和吸热反应的热量之比,以及它们各自的活化能之比。本文旨在探讨这些参数如何影响这些反应前沿的稳态及其稳定性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
ONE-DIMENSIONAL CHAOTIC LAMINAR FLOW WITH COMPETITIVE EXOTHERMIC AND ENDOTHERMIC REACTIONS
Abstract We consider the numerical solution of competitive exothermic and endothermic reactions in the presence of a chaotic advection flow. The resulting behaviour is characterized by a strong dependence on the competitive reaction history. The burnt temperature is not immediately connected to simple enthalpy calculations, so there is a subtlety in the interplay between the major parameters, notably the Damköhler number, the ratio of the heats of exothermic and endothermic reactions, as well as the ratio of their respective activation energies. This paper seeks to explore the way these parameters affect the steady states of these reaction fronts and their stability.
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