{"title":"手性α-乙基苯基胺酒石酸盐的新应用——前手性醛的氰硅化反应","authors":"L. Mei, Z. Hai, Y. Hao, S. Jie, H. Liang","doi":"10.2174/1876214X01003010087","DOIUrl":null,"url":null,"abstract":"The � -ethylphenylamine tartaric acid salts 1a-1d were synthesized from R-(+)/S-(-)-� -ethylphenylamine by reacting with (2S,3S)-(+)/(2R,3R)-(-) dihydrobutanedioic acid. They were used as the catalysts in cyanosilylation of prochiral aldehydes to give the corresponding cyanohydrin trimethylsilyl ethers in moderate conversion at room","PeriodicalId":22755,"journal":{"name":"The Open Catalysis Journal","volume":"32 1","pages":"87-91"},"PeriodicalIF":0.0000,"publicationDate":"2010-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"The Novel Application of Chiral α-Ethylphenyl Amine Tartaric Acid Salts-Cyanosilylation of Prochiral Aldehydes\",\"authors\":\"L. Mei, Z. Hai, Y. Hao, S. Jie, H. Liang\",\"doi\":\"10.2174/1876214X01003010087\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The � -ethylphenylamine tartaric acid salts 1a-1d were synthesized from R-(+)/S-(-)-� -ethylphenylamine by reacting with (2S,3S)-(+)/(2R,3R)-(-) dihydrobutanedioic acid. They were used as the catalysts in cyanosilylation of prochiral aldehydes to give the corresponding cyanohydrin trimethylsilyl ethers in moderate conversion at room\",\"PeriodicalId\":22755,\"journal\":{\"name\":\"The Open Catalysis Journal\",\"volume\":\"32 1\",\"pages\":\"87-91\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2010-10-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Open Catalysis Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2174/1876214X01003010087\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Open Catalysis Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/1876214X01003010087","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The Novel Application of Chiral α-Ethylphenyl Amine Tartaric Acid Salts-Cyanosilylation of Prochiral Aldehydes
The � -ethylphenylamine tartaric acid salts 1a-1d were synthesized from R-(+)/S-(-)-� -ethylphenylamine by reacting with (2S,3S)-(+)/(2R,3R)-(-) dihydrobutanedioic acid. They were used as the catalysts in cyanosilylation of prochiral aldehydes to give the corresponding cyanohydrin trimethylsilyl ethers in moderate conversion at room
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