{"title":"非离子型碳氢化合物和氟碳表面活性剂及其三元混合物水溶液的无限稀释活度系数","authors":"Katarzyna Szymczyka, Anna Tarabab","doi":"10.1515/umcschem-2015-0008","DOIUrl":null,"url":null,"abstract":"Abstract Activity coefficients at infinite dilution of the aqueous solutions of nonionic hydrocarbon surfactants, p-(1,1,3,3- tetramethylbutyl) phenoxypoly(ethylene glycols), Triton X-100 (TX100) and Triton X-165 (TX165), fluorocarbon surfactants, Zonyl FSN-100 (FSN100) and Zonyl FSO-100 (FSO100) and their ternary mixtures were determined from the Gracia-Fadrique et al. method for non-volatile compounds. The values of activity coefficients were calculated taking into account the surface tension data of the studied systems at 293K and compared to those determined on the basis of the values of the contact angle of solutions on the polytetrafluoroethylene (PTFE) and polymethyl methacrylate (PMMA) surfaces and the solid-liquid interface tension.","PeriodicalId":7937,"journal":{"name":"Annales UMCS, Chemia","volume":"251 1","pages":"111 - 124"},"PeriodicalIF":0.0000,"publicationDate":"2015-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Activity coefficient at infinite dilution of aqueous solutions of nonionic hydrocarbon and fluorocarbon surfactants as well as their ternary mixtures\",\"authors\":\"Katarzyna Szymczyka, Anna Tarabab\",\"doi\":\"10.1515/umcschem-2015-0008\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Activity coefficients at infinite dilution of the aqueous solutions of nonionic hydrocarbon surfactants, p-(1,1,3,3- tetramethylbutyl) phenoxypoly(ethylene glycols), Triton X-100 (TX100) and Triton X-165 (TX165), fluorocarbon surfactants, Zonyl FSN-100 (FSN100) and Zonyl FSO-100 (FSO100) and their ternary mixtures were determined from the Gracia-Fadrique et al. method for non-volatile compounds. The values of activity coefficients were calculated taking into account the surface tension data of the studied systems at 293K and compared to those determined on the basis of the values of the contact angle of solutions on the polytetrafluoroethylene (PTFE) and polymethyl methacrylate (PMMA) surfaces and the solid-liquid interface tension.\",\"PeriodicalId\":7937,\"journal\":{\"name\":\"Annales UMCS, Chemia\",\"volume\":\"251 1\",\"pages\":\"111 - 124\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2015-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Annales UMCS, Chemia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1515/umcschem-2015-0008\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Annales UMCS, Chemia","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/umcschem-2015-0008","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Activity coefficient at infinite dilution of aqueous solutions of nonionic hydrocarbon and fluorocarbon surfactants as well as their ternary mixtures
Abstract Activity coefficients at infinite dilution of the aqueous solutions of nonionic hydrocarbon surfactants, p-(1,1,3,3- tetramethylbutyl) phenoxypoly(ethylene glycols), Triton X-100 (TX100) and Triton X-165 (TX165), fluorocarbon surfactants, Zonyl FSN-100 (FSN100) and Zonyl FSO-100 (FSO100) and their ternary mixtures were determined from the Gracia-Fadrique et al. method for non-volatile compounds. The values of activity coefficients were calculated taking into account the surface tension data of the studied systems at 293K and compared to those determined on the basis of the values of the contact angle of solutions on the polytetrafluoroethylene (PTFE) and polymethyl methacrylate (PMMA) surfaces and the solid-liquid interface tension.
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