薄膜加工中的流变学(2)-薄膜铸造过程中的流动不稳定性

H. Ishihara, M. Shibaya, Kosuke Ikeda
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引用次数: 1

摘要

薄膜铸造是获得塑料薄膜产品的重要工艺之一。熔融聚合物铸造是通过冷却放置在挤出模具下方的冷辊表面的挤出熔体来进行的。薄膜浇注过程中的流动不稳定性可分为两类。一种是剪切流失稳,另一种是伸展流失稳。这些不稳定性与熔体纺丝过程中出现的不稳定性相似。在控制剪切流动不稳定性的众多参数中,剪切速率和黛博拉数(定义为聚合物在模具或喷丝孔中的松弛时间与保留时间之比)可能是最重要的。较小的底波拉数可以有效地抑制剪切流动的不稳定性。针对拉伸流动失稳,对拉伸共振现象进行了总结和讨论。低功率流体模型中的低功率指数和麦克斯韦流体模型中的弛豫时间等聚合物参数对拉伸共振失稳的发生有重要影响。作为工艺参数,挤压熔体的冷却效果、拉伸比(熔体伸长率)和气隙长度(从模具出口到冷辊的距离)也很重要。进一步研究了不同频率扰动的瞬态响应。发现膜厚均匀性随扰动频率的变化而变化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Rheology in Film Processing (2)-Flow Instabilities in Film Casting Process-
Film casting is one of the important processes for obtaining the plastic film products. Molten polymer casting is conducted by cooling the extruded melts at the surface of chill roller laid below the extrusion dies. Flow instabilities in the film casting are divided into two categories. One is the shear flow instability and the other is the extensional flow instability. These instabilities are similar to those appearing in the melt spinning process. Among many parameters governing shear flow instability, shear rate and Deborah number defined as the ratio of polymer relaxation time to retention time in the land of dies or spinneret orifice are likely to be most important. The small value of Deborah number is found to be effective for depressing the shear flow instability. Regarding the extensional flow instability, draw resonance phenomena were summarized and discussed. Polymer parameters such as power low index in the power low fluid model and relaxation time in Maxwell fluid model were found to be important for onset of draw resonance instability. As process parameters, cooling effect of extruded melts, draft ratio defined as elongation ratio of melts and air gap length corresponding the distance from dies exit to chill roller were also important. Further study on transient response of disturbances having various frequencies was done. It was found that film thickness uniformity changed depending on disturbance frequency.
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