电子圆二色性的特征及其用于确定绝对形状的提示

Q2 Chemistry

Tetrahedron, asymmetry Pub Date : 2017-10-15 DOI:10.1016/j.tetasy.2017.09.015

Jesús T. Vázquez

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引用次数: 19

摘要

本文综述了电子圆二色性(ECD)在确定有机化合物绝对构型方面的一般特点。激子手性方法的高灵敏度和直接的光谱解释使该方法非常有用，并与x射线晶体学相补充。简要介绍了ECD的使用注意事项和技巧，特别是激子手性法。对几个例子的光谱ECD进行了分析。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Features of electronic circular dichroism and tips for its use in determining absolute configuration

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Features of electronic circular dichroism and tips for its use in determining absolute configuration

This review focuses on the general features of electronic circular dichroism (ECD) as applied in determining the absolute configuration of organic compounds. The high sensitivity and straightforward spectral interpretation of the exciton chirality method makes this approach very useful, and complementary to X-ray crystallography. A brief tutorial is provided on ECD, with precautions and tips for using it, especially the exciton chirality method. The spectroscopic ECD of several examples are analyzed.

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来源期刊

Tetrahedron, asymmetry 化学-无机化学与核化学

CiteScore

4.70

自引率

0.00%

发文量

审稿时长

1 months

期刊介绍： Cessation. Tetrahedron: Asymmetry presents experimental or theoretical research results of outstanding significance and timeliness on asymmetry in organic, inorganic, organometallic and physical chemistry, as well as its application to related disciplines, especially bio-organic chemistry. The journal publishes critical reviews, original research articles and preliminary communications dealing with all aspects of the chemical, physical and theoretical properties of non-racemic organic and inorganic materials and processes. Topics relevant to the journal include: the physico-chemical and biological properties of enantiomers; strategies and methodologies of asymmetric synthesis; resolution; chirality recognition and enhancement; analytical techniques for assessing enantiomeric purity and the unambiguous determination of absolute configuration; and molecular graphics and modelling methods for interpreting and predicting asymmetric phenomena. Papers describing the synthesis or properties of non-racemic molecules will be required to include a separate statement in the form of a Stereochemistry Abstract, for publication in the same issue, of the criteria used for the assignment of configuration and enantiomeric purity.