电厂中肼的暴露及其控制

T. Kauppinen, J. Alho, L. Lindroos
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摘要

摘要:通过邮政调查,对电厂中肼的使用情况进行了调查,以检测在处理肼时使用替代技术程序时暴露的差异。根据空气中肼的浓度和通过皮肤的潜在吸收,估计了八家工厂员工的暴露水平。问卷发放至288家电厂,回收264家电厂,其中100家电厂使用联氨。约500名员工服用并稀释了浓(15%或35%)联氨溶液。在较大的工厂,通常是用泵或喷射器给药,而在较小的工厂,则是用测量仪给药。联氨处理室空气中联氨浓度:计量加药< 0.01 ~ 0.06 ppm(平均< 0.02 ppm);泵加药< 0.01-0.37 PPM(平均0.12 PPM);喷射器加药< 0.01-0.33 PPM(平均0.09 PPM),罐未关闭;在< 0.01-0.04 PPM(平均0.02 PPM)范围内加药,有喷射器,罐体封闭并配有排气装置。此时……
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Exposure to Hydrazine and its Control in Power Plants
Abstract The use of hydrazine in power plants was surveyed with a postal inquiry to detect differences in exposure when alternative technical procedures were used in the handling of hydrazine. The exposure level of employees in eight plants was estimated based on the concentration of hydrazine in the air and the potential absorption through the skin. The questionnaire was sent to 288 power plants and 264 were returned, 100 of which used hydrazine. About 500 employees dosed and diluted strong (15% or 35%) hydrazine solution. The dosing was usually done with a pump or an ejector in bigger plants and with a measure in small plants. The airborne hydrazine concentrations in the rooms where hydrazine was handled were: < 0.01–0.06 ppm (mean < 0.02 ppm) for dosing with measure; < 0.01–0.37 ppm (mean 0.12 ppm) for dosing with pump; < 0.01–0.33 ppm (mean 0.09 ppm) for dosing with ejector, tank not closed; and < 0.01–0.04 ppm (mean 0.02 ppm) for dosing with ejector, tank closed and equipped with exhaust. The time-we...
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