{"title":"(C3H5NH3)2H2P2O7·H2O的结构","authors":"E.H. Soumhi , I. Saadoune , A. Driss , T. Jouini","doi":"10.1016/S0992-4361(99)80010-1","DOIUrl":null,"url":null,"abstract":"<div><p>The bis(cyclopropylammonium)dihydrogenodiphosphate monohydrate is a new diphosphate associated with the organic molecule C<sub>3</sub>H<sub>5</sub>NH<sub>2</sub>. We report the chemical preparation and the crystal structure of this organic cation diphosphate. (C<sub>3</sub>H<sub>5</sub>NH<sub>3</sub>)<sub>2</sub>H<sub>2</sub>P<sub>2</sub>O<sub>7</sub>.H<sub>2</sub>O is orthorhombic (S.G. : P2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>), with Z = 4 and the following unit-cell parameters : a = 4.828(1) Å, b = 11.011(1) Å, c = 25.645(2) Å. The P<sub>2</sub>O<sub>7</sub> groups and H<sub>2</sub>O water molecules form a succession of bidimensional layers perpendicular to the c axis. The organic cations ensure the three-dimensional cohesion by NH-O hydrogen bonds.</p></div>","PeriodicalId":100507,"journal":{"name":"European Journal of Solid State and Inorganic Chemistry","volume":"35 10","pages":"Pages 699-706"},"PeriodicalIF":0.0000,"publicationDate":"1998-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0992-4361(99)80010-1","citationCount":"1","resultStr":"{\"title\":\"Structure of (C3H5NH3)2H2P2O7·H2O\",\"authors\":\"E.H. Soumhi , I. Saadoune , A. Driss , T. Jouini\",\"doi\":\"10.1016/S0992-4361(99)80010-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The bis(cyclopropylammonium)dihydrogenodiphosphate monohydrate is a new diphosphate associated with the organic molecule C<sub>3</sub>H<sub>5</sub>NH<sub>2</sub>. We report the chemical preparation and the crystal structure of this organic cation diphosphate. (C<sub>3</sub>H<sub>5</sub>NH<sub>3</sub>)<sub>2</sub>H<sub>2</sub>P<sub>2</sub>O<sub>7</sub>.H<sub>2</sub>O is orthorhombic (S.G. : P2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>), with Z = 4 and the following unit-cell parameters : a = 4.828(1) Å, b = 11.011(1) Å, c = 25.645(2) Å. The P<sub>2</sub>O<sub>7</sub> groups and H<sub>2</sub>O water molecules form a succession of bidimensional layers perpendicular to the c axis. The organic cations ensure the three-dimensional cohesion by NH-O hydrogen bonds.</p></div>\",\"PeriodicalId\":100507,\"journal\":{\"name\":\"European Journal of Solid State and Inorganic Chemistry\",\"volume\":\"35 10\",\"pages\":\"Pages 699-706\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0992-4361(99)80010-1\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Solid State and Inorganic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0992436199800101\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Solid State and Inorganic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0992436199800101","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
摘要
二(环丙基铵)二氢二磷酸一水合物是一种与有机分子C3H5NH2相结合的新型二磷酸盐。本文报道了这种有机阳离子二磷酸的化学制备及其晶体结构。(C3H5NH3) 2 h2p2o7。H2O是正交的(S.G.: P212121)， Z = 4，单位胞参数为:a = 4.828(1) Å， b = 11.011(1) Å， c = 25.645(2) Å。P2O7基团和H2O水分子形成一系列垂直于c轴的二维层。有机阳离子通过NH-O氢键保证三维内聚。
The bis(cyclopropylammonium)dihydrogenodiphosphate monohydrate is a new diphosphate associated with the organic molecule C3H5NH2. We report the chemical preparation and the crystal structure of this organic cation diphosphate. (C3H5NH3)2H2P2O7.H2O is orthorhombic (S.G. : P212121), with Z = 4 and the following unit-cell parameters : a = 4.828(1) Å, b = 11.011(1) Å, c = 25.645(2) Å. The P2O7 groups and H2O water molecules form a succession of bidimensional layers perpendicular to the c axis. The organic cations ensure the three-dimensional cohesion by NH-O hydrogen bonds.
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