活性炭的评价与利用研究(二)

K. Terada, K. Kudo, Yojiro Yamamoto, Mitsuyuki Mitooka, A. Yokogawa
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引用次数: 0

摘要

研究了磺化沥青制备活性炭的液相吸附性能,并与市售活性炭进行了比较。吸附剂有碘、乙酸、苯酚、亚甲基蓝、十二烷基苯磺酸钠、罗丹明B、刚果红、氯化甲基汞、硝酸铅和氰酸钠。对碘、乙酸等小分子吸附剂的吸附能力与原料沥青的产率几乎无关,与商品活性炭的吸附能力相同。另一方面,对亚甲基蓝、DBS、刚果红等大分子吸附剂的吸附量随着收率的降低而增加。对于这种大分子吸附剂,活性炭的收率保持在30%以下,具有与商品活性炭相当的大吸附容量。磺化沥青中活性炭的吸附速率和颗粒内扩散系数均大于商用沥青。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Studies on Evaluation and Utilization of Activated Carbon (Part 2)
Liquid phase adsorption properties of activated carbon prepared from sulfonated asphalt were investigated by comparing with those of commercial activated carbon. As adsorbates iodine, acetic acid, phenol, methylene blue, sodium dodecylbenzene sulfonate (DBS), rhodamine B, congo red, methyl mercury chloride, lead nitrate and sodium cyanate were used.Adsorption capacity for comparatively small molecular adsorbates such as iodine and acetic acid was almost independent of the yield from raw asphalt and it was the same order of magnitude of commercial activated carbon.On the other hand, adsorption capacity for comparatively large molecular adsorbates such as methylene blue, DBS and congo red increased with decreasing yield. Activated carbon, yield was kept less than 30%, was found to have large adsorption capacity comparable to that of commercial activated carbon for such large molecular adsorbates.The adsorption rate and intraparticle diffusion coefficient for activated carbon from sulfonated asphalt were found to be larger than those for commercial ones.
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