有机合成中的多磷酸

Lisbeth Mendoza, Liadis Bedoya, Elvia V. Cabrera, D. Arrieche, A. K. Banerjee
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引用次数: 1

摘要

聚磷酸(PPA)是一种强脱水剂,被广泛用于多种重要的有机反应,在有机化合物和天然产物的合成中起着重要的作用。本文简要介绍了PPA(1)在芳香环上酸的环化(2)在芳香环上的乙酰化和异丙基化,(3)酯的水解,(4)环氧化合物的裂解和(5)杂环化合物的合成中的应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Polyphosphoric Acid in Organic Synthesis
Polyphosphoric acid (PPA), a powerful dehydrating agent, has been widely used to perform several important organic reactions and thus has played an important role in the synthesis of organic compounds and natural products. The present micro review describes briefly the use of PPA (i) in the cyclization of acids on the aromatic ring (ii) in acetylation and isopropylation on the aromatic ring, (iii)hydrolysis of esters, (iv) cleavage of epoxides and (v) synthesis of heterocyclic compounds.
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