{"title":"金属氧化物的添加或掺杂对AgSnO/ sub2 /触点材料电性能的影响","authors":"D. Jeannot, J. Pinard, P. Ramoni, E. Jost","doi":"10.1109/HOLM.1993.489660","DOIUrl":null,"url":null,"abstract":"The new contact material AgSnO/sub 2/, which is replacing AgCdO in many applications, requires the addition of doping agents to improve electrical contact performance. These additions effect thermodynamic stability, wettability of the SnO/sub 2/ surface by liquid silver as well as the microstructure of the area melted by the electric arc. This work considers the frequently used dopants WO/sub 3/, MoO/sub 3/, Bi/sub 2/O/sub 3/, CuO and RuO/sub 2/ as well as others: ZnO, Ta/sub 2/O/sub 5/, HgO, RuO/sub 2/, Sb/sub 2/O/sub 3/, TeO/sub 2/ and TaC. DTA and TGA analyses are performed on mixtures of these metal oxides with SnO/sub 2/, Ag and AgSnO/sub 2/. Reaction products, if present, are characterized by X-ray diffraction. The wetting angles of molten silver on surfaces of these mixtures are established. The results are used to interpret the microstructures found in the molten regions of AgSnO/sub 2/ materials doped with these substances. These structures are interpreted and related to performance in arcing contact applications.","PeriodicalId":11624,"journal":{"name":"Electrical Contacts - 2007 Proceedings of the 53rd IEEE Holm Conference on Electrical Contacts","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1993-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"12","resultStr":"{\"title\":\"The effects of metal oxide additions or dopants on the electrical performance of AgSnO/sub 2/ contact materials\",\"authors\":\"D. Jeannot, J. Pinard, P. Ramoni, E. Jost\",\"doi\":\"10.1109/HOLM.1993.489660\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The new contact material AgSnO/sub 2/, which is replacing AgCdO in many applications, requires the addition of doping agents to improve electrical contact performance. These additions effect thermodynamic stability, wettability of the SnO/sub 2/ surface by liquid silver as well as the microstructure of the area melted by the electric arc. This work considers the frequently used dopants WO/sub 3/, MoO/sub 3/, Bi/sub 2/O/sub 3/, CuO and RuO/sub 2/ as well as others: ZnO, Ta/sub 2/O/sub 5/, HgO, RuO/sub 2/, Sb/sub 2/O/sub 3/, TeO/sub 2/ and TaC. DTA and TGA analyses are performed on mixtures of these metal oxides with SnO/sub 2/, Ag and AgSnO/sub 2/. Reaction products, if present, are characterized by X-ray diffraction. The wetting angles of molten silver on surfaces of these mixtures are established. The results are used to interpret the microstructures found in the molten regions of AgSnO/sub 2/ materials doped with these substances. These structures are interpreted and related to performance in arcing contact applications.\",\"PeriodicalId\":11624,\"journal\":{\"name\":\"Electrical Contacts - 2007 Proceedings of the 53rd IEEE Holm Conference on Electrical Contacts\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1993-09-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"12\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Electrical Contacts - 2007 Proceedings of the 53rd IEEE Holm Conference on Electrical Contacts\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/HOLM.1993.489660\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrical Contacts - 2007 Proceedings of the 53rd IEEE Holm Conference on Electrical Contacts","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/HOLM.1993.489660","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The effects of metal oxide additions or dopants on the electrical performance of AgSnO/sub 2/ contact materials
The new contact material AgSnO/sub 2/, which is replacing AgCdO in many applications, requires the addition of doping agents to improve electrical contact performance. These additions effect thermodynamic stability, wettability of the SnO/sub 2/ surface by liquid silver as well as the microstructure of the area melted by the electric arc. This work considers the frequently used dopants WO/sub 3/, MoO/sub 3/, Bi/sub 2/O/sub 3/, CuO and RuO/sub 2/ as well as others: ZnO, Ta/sub 2/O/sub 5/, HgO, RuO/sub 2/, Sb/sub 2/O/sub 3/, TeO/sub 2/ and TaC. DTA and TGA analyses are performed on mixtures of these metal oxides with SnO/sub 2/, Ag and AgSnO/sub 2/. Reaction products, if present, are characterized by X-ray diffraction. The wetting angles of molten silver on surfaces of these mixtures are established. The results are used to interpret the microstructures found in the molten regions of AgSnO/sub 2/ materials doped with these substances. These structures are interpreted and related to performance in arcing contact applications.
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