溶液中分子间氢键分子配合物的超快相干振动响应

E. Nibbering, N. Huse, K. Heyne, T. Elsaesser
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引用次数: 0

摘要

在中红外泵浦探测和光子回波实验中观察到分子间氢键的相干振动运动。底层的低频模式与O-H拉伸模式非谐波耦合,并且比O-H拉伸模式退化得慢得多。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Ultrafast coherent vibrational response of intermolecular hydrogen bonded molecular complexes in solution
Coherent vibrational motions along intermolecular hydrogen bonds are observed in mid-infrared pump-probe and photon echo experiments. The underlying low-frequency modes couple anharmonically to the O-H stretching mode and dephase much slower than the O-H stretching mode.
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