化学法制备不同比例(Fe2+)掺杂氧化铜(CuO) NPs的合成与表征

. N.Subhalakshmi, . M.Karunakaran, . K.Kasirajan, . N.Ganeshwari
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引用次数: 3

摘要

近十年来,金属氧化物纳米粒子在研究领域的应用前景十分广阔。合成NPs的方法有很多,但共沉淀法非常简单,成本低,对环境友好。用共沉淀法制备了不同比例(fe2 +)掺杂的氧化铜(CuO) NPs。XRD谱图证实样品为单斜晶型,经JCPDS卡鉴定。没有(80 - 0076)。掺杂浓度越大,晶粒尺寸越小。用FTIR光谱鉴定了CuO NPs基官能团。紫外可见光谱法测定了Fe掺杂CuO在3.57 ~ 3.62 eV范围内的带隙。在CuO结构中引入Fe后,Pl发射光谱出现蓝移,有利于制备CuO纳米粒子。SEM研究了制备的CuO纳米颗粒的表面形貌,观察到不确定且紧密排列的晶粒。EDAX光谱显示了铜、铁和氧原子的存在。关键词:共沉淀,掺杂,氧化铜,结构研究,带隙。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and characterization of different percentage (Fe2+) doped copper oxide (CuO) NPs prepared by chemical method
In the last decade the metal oxide NPs are the promising applications in the research field. The lot of methods to available in the synthesis of NPs, but co-precipitation method is very simple, low cost and environmental friendly. The different percentage (Fe 2+ ) doped copper oxide (CuO) NPs prepared by co-precipitation method. XRD pattern confirms the samples are crystalline in monoclinic structure identified by the JCPDS Card. No (80-0076). The doping concentration increases the crystalline size also decreases. CuO NPs based functional groups are identified from FTIR spectra. UV-Vis Spectroscopy the Fe doped CuO has a band gap is determined in the range of 3.57 to 3.62 eV. The Pl emission spectra revealed a blue shift after introducing Fe into CuO structure, from these studies is better for the preparation of CuO nanoparticles. SEMthe surface morphology of the as prepared CuO nanoparticles has identified by SEM studies the indefinite and closely packed grain is observed. The EDAX spectra showed presence copper, Fe and oxygen atoms. Keywords— Co-Precipitation, Doping, Copper Oxide, Structural Studies, Band gap.
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