{"title":"溶剂中c60臭氧化产生的不稳定产物","authors":"D. Heymann, F. Cataldo","doi":"10.1081/FST-100000166","DOIUrl":null,"url":null,"abstract":"The ozonation of a solution of C60 in toluene results in the formation of several unstable compounds C60X and C60Y[1–5] which decay completely at room temperature within about 1 h. The products are oxides C60O[6,6], C60O2[I], C60O2[II], and possibly an isomer of C60O3. The transformations are not due to oxidation by atmospheric oxygen but are spontaneous. The ozonation of a solution of C60O[6,6] in toluene results in the formation of two unstable compounds C60Z[1–2] which also decay completely to C60O2[I] and C60O2[II]. It is suggested that all unstable “parents” are ozonides.","PeriodicalId":12470,"journal":{"name":"Fullerene Science and Technology","volume":"39 1","pages":"71 - 76"},"PeriodicalIF":0.0000,"publicationDate":"2001-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"UNSTABLE PRODUCTS FROM THE OZONATION OF C60 IN SOLVENTS\",\"authors\":\"D. Heymann, F. Cataldo\",\"doi\":\"10.1081/FST-100000166\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The ozonation of a solution of C60 in toluene results in the formation of several unstable compounds C60X and C60Y[1–5] which decay completely at room temperature within about 1 h. The products are oxides C60O[6,6], C60O2[I], C60O2[II], and possibly an isomer of C60O3. The transformations are not due to oxidation by atmospheric oxygen but are spontaneous. The ozonation of a solution of C60O[6,6] in toluene results in the formation of two unstable compounds C60Z[1–2] which also decay completely to C60O2[I] and C60O2[II]. It is suggested that all unstable “parents” are ozonides.\",\"PeriodicalId\":12470,\"journal\":{\"name\":\"Fullerene Science and Technology\",\"volume\":\"39 1\",\"pages\":\"71 - 76\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2001-02-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fullerene Science and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/FST-100000166\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fullerene Science and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/FST-100000166","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
UNSTABLE PRODUCTS FROM THE OZONATION OF C60 IN SOLVENTS
The ozonation of a solution of C60 in toluene results in the formation of several unstable compounds C60X and C60Y[1–5] which decay completely at room temperature within about 1 h. The products are oxides C60O[6,6], C60O2[I], C60O2[II], and possibly an isomer of C60O3. The transformations are not due to oxidation by atmospheric oxygen but are spontaneous. The ozonation of a solution of C60O[6,6] in toluene results in the formation of two unstable compounds C60Z[1–2] which also decay completely to C60O2[I] and C60O2[II]. It is suggested that all unstable “parents” are ozonides.
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