三配位锌阳离子的合成及其催化活性

Mark D. Hannant, M. Schormann, M. Bochmann
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引用次数: 69

摘要

DADZnR2与B(C6F5)3或ZnR2与[DADH][B(C6F5)4]反应产生三配位烷基和酰胺锌阳离子,它们对环氧化物和e-己内酯的开环聚合具有活性[DAD = (mecnc6h3pri2 -2,6)2]。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and catalytic activity of three-coordinate zinc cations
Reaction between DADZnR2 and either B(C6F5)3 or ZnR2 and [DADH][B(C6F5)4] affords three-coordinate alkyl and amide zinc cations which are active for the ring opening polymerisation of epoxides and e-caprolactone [DAD = (MeCNC6H3Pri2-2,6)2].
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