钒:生物、环境和工程方面

D. Rehder
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引用次数: 1

摘要

钒是一种广泛分布于地壳、海水和地下水中的元素。因此,它对与生命和环境有关的问题产生了很大的影响。钒被几种海洋生物利用。例如,藻类和几种细菌(如固氮细菌)中存在钒酸盐依赖的卤素过氧化物酶,它们利用钒酸盐进行固氮,细菌还原涉及将钒酸盐转化为氧化钒(IV)。钒酸盐和磷酸盐之间的相似性赋予了钒酸盐(V)生理功能作用,因此,钒酸盐和钒配位化合物在几个方面具有药用潜力,例如它们在治疗糖尿病、癌症、心血管问题,这可能与钒酸盐/磷酸盐拮抗作用有关。类似的考虑也适用于钒化合物在治疗艾滋病毒和由细菌和原生动物引起的[热带]疾病方面的功效。除了这种生物功效外,钒在工业过程中也发挥着越来越重要的作用,如钢铁生产、氧化催化、钒基储能(电池)和太阳能电池。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Vanadium: Biological, Environmental, and Engineering Aspects
Vanadium is an element that is widely distributed in Earth’s crust as well as in sea-water and ground-water reservoirs. Therefore, it exerts a great influence on the issues related to life and environment. Vanadium is utilized by several marine organisms. For example, there are vanadate-dependent haloperoxidases in algae and several bacteria, e.g., Azotobacter, use it for nitrogen fixation and bacterial reduction involves the conversion of vanadate to oxidovanadium (IV). The similarity between vanadate and phosphate imparts a physiological functional role to vanadate (V), and consequently, several aspects of medicinal potential to vanadate and vanadium coordination compounds, such as their use in the treatment of diabetes, cancer, and cardiovascular problems, which may be explained in conjunction with vanadate/phosphate antagonism. Similar considerations apply to the efficacy of vanadium compounds in the treatment of HIV and [tropical] diseases caused by bacteria and protozoa. In addition to this biological efficacy, vanadium plays an increasingly recognized role in industrial processes, such as steel production, oxidation catalysis, and vanadium-based energy storage (batteries) and solar cells.
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