{"title":"芳族化合物的放射性溴化裂解芳基锡键","authors":"M.J. Adam, T.J. Ruth, Y. Homma , B.D. Pate","doi":"10.1016/0020-708X(85)90250-9","DOIUrl":null,"url":null,"abstract":"<div><p>Radiobrominated (<sup>77,82</sup>Br) aromatic compounds were synthesized by the cleavage of aryl-tin derivatives with oxidized low specific activity <sup>82</sup>Br or no-carrier-added (NCA) [<sup>77</sup>Br]bromide. Both chloramine-T and N-chlorosuccinimide, when used as oxidants, gave near quantitative yields within 5 min.</p></div>","PeriodicalId":22517,"journal":{"name":"The International journal of applied radiation and isotopes","volume":"36 12","pages":"Pages 935-937"},"PeriodicalIF":0.0000,"publicationDate":"1985-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-708X(85)90250-9","citationCount":"18","resultStr":"{\"title\":\"Radiobromination of aromatic compounds by cleavage of aryl-tin bonds\",\"authors\":\"M.J. Adam, T.J. Ruth, Y. Homma , B.D. Pate\",\"doi\":\"10.1016/0020-708X(85)90250-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Radiobrominated (<sup>77,82</sup>Br) aromatic compounds were synthesized by the cleavage of aryl-tin derivatives with oxidized low specific activity <sup>82</sup>Br or no-carrier-added (NCA) [<sup>77</sup>Br]bromide. Both chloramine-T and N-chlorosuccinimide, when used as oxidants, gave near quantitative yields within 5 min.</p></div>\",\"PeriodicalId\":22517,\"journal\":{\"name\":\"The International journal of applied radiation and isotopes\",\"volume\":\"36 12\",\"pages\":\"Pages 935-937\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-708X(85)90250-9\",\"citationCount\":\"18\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The International journal of applied radiation and isotopes\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020708X85902509\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The International journal of applied radiation and isotopes","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020708X85902509","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Radiobromination of aromatic compounds by cleavage of aryl-tin bonds
Radiobrominated (77,82Br) aromatic compounds were synthesized by the cleavage of aryl-tin derivatives with oxidized low specific activity 82Br or no-carrier-added (NCA) [77Br]bromide. Both chloramine-T and N-chlorosuccinimide, when used as oxidants, gave near quantitative yields within 5 min.