热解对醇氧阴离子反应的影响

Geneviève Boand, Raymond Houriet, Tino Gäumann
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引用次数: 1

摘要

产物在醇的负化学电离谱中的分布不受热解反应的影响(<1%)。另一方面,表明缓慢的离子/分子反应可以被快速的过程所掩盖,这意味着热解形成的杂质。讨论了抽运速度在离子回旋共振(ICR)光谱仪中的重要性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Pyrolysis effects on the reactions of alkoxide anions

The distribution of products in negative chemical-ionization spectra of alcohols are shown to remain unaffected (<1%) by pyrolytic reactions. On the other hand, it is shown that slow ion/molecule reactions can be obscured by fast processes implying impurities formed by pyrolysis. The importance of pumping speed in ion cyclotron resonance (ICR) spectrometers is also discussed.

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