碳化硅对砂岩层表面张力及SDS吸附的影响

Anurag Pandey, Vishnu Roy, H. Kesarwani, Govind Mittal, Shivanjali Sharma, Anika Saxena
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引用次数: 1

摘要

由于储层的复杂性和非均质性,现代油田的采油具有挑战性。需要提高添加剂在高压、高温、高盐度条件下的油动员效果。纳米颗粒为提高石油采收率提供了改进的、可持续的解决方案。碳化硅纳米颗粒具有可忽略不计的团聚现象,并且在高盐度条件下对驱替液具有较高的热稳定性,有利于油的动员。SIC纳米颗粒由于其在高温下的吸附还原潜力和热稳定性,首次被用于提高采收率。该研究估计,通过电导率、表面张力降低和原油动员,这种纳米颗粒具有提高采收率的潜力。SDS的浓度在0 ~ 4000 ppm之间变化,SIC的浓度在100 ~ 300 ppm之间变化。在高温(30°C、50°C和70°C)下,测量了溶液的表面张力和临界胶束浓度(CMC)电导率。在溶液中加入10 wt%的沙子,进行72小时的吸附研究。通过研究表面活性剂吸附前后的电导率变化,计算了表面活性剂在砂土上的损失。随着溶液中SDS和纳米颗粒浓度的增加,表面张力从70.15 mN/m降低到28.5 mN/m。SDS+SIC溶液的CMC值低于独立表面活性剂体系,即使在70℃的高温下也是如此。当表面活性剂浓度增加到4000 ppm时,SDS的吸附从0.80 mg/g增加到6.27 mg/g。当纳米颗粒含量为100 ppm和200 ppm时,其含量分别降低了10%和20%。然而,在300ppm时,纳米颗粒的团聚使它们在控制吸附方面无效。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Silicon Carbide on the Surface Tension and Adsorption of SDS on the Sandstone Formation
Oil recovery in modern fields is challenging due to the reservoir complexity and heterogeneity. The need is to improve the efficacy of additives used in oil mobilization under higher pressure, temperature, and salinity conditions. The nanoparticles provide improved and sustainable solutions for improving oil recovery. Silicon carbide nanoparticle exhibits negligible agglomeration and impart higher thermal stability to the displacing fluid for oil mobilization at higher salinity. The SIC nanoparticles are being used in EOR Applications for the first time owing to their adsorption reduction potential and thermal stability at elevated temperatures. The study estimates this nanoparticle's enhanced oil recovery potential using electrical conductivity, surface tension reduction, and crude oil mobilization. The concentration of SDS was varied from zero-4000 ppm and that of SIC from 100 ppm to 300 ppm. The solution's surface tension and critical micelle concentration (CMC) conductivity were measured at elevated temperatures (30°C, 50°C, and 70°C) with and without nanoparticles. The adsorption studies were performed for 72 hours with 10 wt% of sand added to the solution. The loss of surfactant onto the sand was calculated by studying the variation electrical conductivity before and after adsorption. Surface tension reduces from 70.15 to 28.5 mN/m with increasing SDS and nanoparticles concentrations in the solution. The CMC values of the SDS+SIC solution were lower than that of the independent surfactant system, even at higher temperatures of 70°C. SDS adsorption increased from 0.80 to 6.27 mg/g as the surfactant concentration increased up to 4000 ppm. It was reduced by about 10% and 20% for 100 ppm and 200 ppm of the nanoparticles. However, at 300 ppm, the agglomeration of nanoparticles renders them ineffective in controlling adsorption.
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