{"title":"四面体阴离子-ⅲ的红外光谱禁跃迁。分子式MXO4的高氯酸盐、硫酸盐和磷酸盐的光谱结构相关性","authors":"A. Hezel, S.D. Ross","doi":"10.1016/0371-1951(66)80183-2","DOIUrl":null,"url":null,"abstract":"<div><p>The spectra of 63 compounds have been recorded as mulls in Nujol and in hexachlorobutadiene and as alkali halide discs. The effect of site symmetry on the gross structure of the spectra and on the intensity of ν<sub>1</sub> is considered; the effect of perturbation by water molecules, and the possibility of covalent bonding in the compounds is also discussed.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 11","pages":"Pages 1949-1961"},"PeriodicalIF":0.0000,"publicationDate":"1966-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80183-2","citationCount":"199","resultStr":"{\"title\":\"Forbidden transitions in the infra-red spectra of tetrahedral anions—III. Spectra-structure correlations in perchlorates, sulphates and phosphates of the formula MXO4\",\"authors\":\"A. Hezel, S.D. Ross\",\"doi\":\"10.1016/0371-1951(66)80183-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The spectra of 63 compounds have been recorded as mulls in Nujol and in hexachlorobutadiene and as alkali halide discs. The effect of site symmetry on the gross structure of the spectra and on the intensity of ν<sub>1</sub> is considered; the effect of perturbation by water molecules, and the possibility of covalent bonding in the compounds is also discussed.</p></div>\",\"PeriodicalId\":101180,\"journal\":{\"name\":\"Spectrochimica Acta\",\"volume\":\"22 11\",\"pages\":\"Pages 1949-1961\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0371-1951(66)80183-2\",\"citationCount\":\"199\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0371195166801832\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166801832","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Forbidden transitions in the infra-red spectra of tetrahedral anions—III. Spectra-structure correlations in perchlorates, sulphates and phosphates of the formula MXO4
The spectra of 63 compounds have been recorded as mulls in Nujol and in hexachlorobutadiene and as alkali halide discs. The effect of site symmetry on the gross structure of the spectra and on the intensity of ν1 is considered; the effect of perturbation by water molecules, and the possibility of covalent bonding in the compounds is also discussed.
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