黄菊花素类黄酮在硫酸溶液中作为低碳钢缓蚀剂的电化学评价

M. Díaz, M. Valladares, E. C. Menchaca, J. Uruchurtu
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引用次数: 1

摘要

近年来研究的重点是天然有机化合物作为金属缓蚀剂,具有良好的防腐性能和效率。在不同植物中存在的一种纯天然类黄酮代谢物Chrysin的情况下,研究了钢在酸性介质中的腐蚀行为。利用极化曲线、电化学阻抗谱(EIS)和恒电位条件下的电化学电流密度对其防腐性能进行了评价。极化曲线表现为活性溶解,在高过电位下存在两个钝化区。在3个不同的阳极电位(-370、+216和+600 mV)下,EIS测量和恒电位曲线显示出轻微的防腐蚀作用,在这两个钝化区域,Chrysin的存在显示出更稳定的钝化膜。在+600 mV下浸泡4小时形成的膜具有很高的防腐性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Electrochemical Evaluation of Chrysin Flavonoid as Corrosion Inhibitor for Mild Steel in Sulphuric Acid Solution
Recently research is focused on natural organic compounds as metallic corrosion inhibitors demonstrating good corrosion protection and efficiencies. Steel corrosion behavior in acid media was evaluated in the presence of a pure natural flavonoid metabolite named Chrysin present in different plants. The evaluation of corrosion protection was studied using polarization curves, electrochemical impedance spectroscopy (EIS) and electrochemical current density under potentiostatic conditions. Polarization curves present active dissolution and at high overpotentials two passivation regions were found. Slight corrosion protection was obtained from EIS measurements and potentiostatic curves at three different anodic potentials: -370, +216 and +600 mV, revealed a more stable passive film in the presence of Chrysin at both passive regions. High corrosion protection was obtained on the film formed at +600 mV during the first 4 hours of immersion.
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