{"title":"3‐Hydrazino‐6‐methyl[1,2,4]triazin‐5(4H)one衍生Schiff碱铜配合物的合成、表征及光化学研究","authors":"A. Osman, M. Saleh, S. Mahmoud","doi":"10.1081/SIM-120039258","DOIUrl":null,"url":null,"abstract":"Abstract Cu(II) complexes of new bidentate and tridentate Schiff bases derived from the condensation of 3‐hydrazino‐6‐methyl[1,2,4]triazin‐5(4H)one and aromatic aldehyde derivatives were synthesized and characterized. The structure of the complexes proposed according to elemental analyses, molar conductance, IR UV‐Visible absorption spectra is square‐planar. The thermodecomposition kinetics of the complexes were investigated under non‐isothermal condition. TG and DTG curves indicated that the complexes decompose in three to six steps. The photochemical behavior of the complexes depends on the substituted group on the aromatic aldehyde. A mechanism has been suggested to account for the recorded results.","PeriodicalId":22160,"journal":{"name":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","volume":"34 1","pages":"1069 - 1085"},"PeriodicalIF":0.0000,"publicationDate":"2004-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"13","resultStr":"{\"title\":\"Synthesis, Characterization, and Photochemical Studies of Some Copper Complexes of Schiff Bases Derived from 3‐Hydrazino‐6‐methyl[1,2,4]triazin‐5(4H)one\",\"authors\":\"A. Osman, M. Saleh, S. Mahmoud\",\"doi\":\"10.1081/SIM-120039258\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Cu(II) complexes of new bidentate and tridentate Schiff bases derived from the condensation of 3‐hydrazino‐6‐methyl[1,2,4]triazin‐5(4H)one and aromatic aldehyde derivatives were synthesized and characterized. The structure of the complexes proposed according to elemental analyses, molar conductance, IR UV‐Visible absorption spectra is square‐planar. The thermodecomposition kinetics of the complexes were investigated under non‐isothermal condition. TG and DTG curves indicated that the complexes decompose in three to six steps. The photochemical behavior of the complexes depends on the substituted group on the aromatic aldehyde. A mechanism has been suggested to account for the recorded results.\",\"PeriodicalId\":22160,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"volume\":\"34 1\",\"pages\":\"1069 - 1085\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2004-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"13\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/SIM-120039258\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/SIM-120039258","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis, Characterization, and Photochemical Studies of Some Copper Complexes of Schiff Bases Derived from 3‐Hydrazino‐6‐methyl[1,2,4]triazin‐5(4H)one
Abstract Cu(II) complexes of new bidentate and tridentate Schiff bases derived from the condensation of 3‐hydrazino‐6‐methyl[1,2,4]triazin‐5(4H)one and aromatic aldehyde derivatives were synthesized and characterized. The structure of the complexes proposed according to elemental analyses, molar conductance, IR UV‐Visible absorption spectra is square‐planar. The thermodecomposition kinetics of the complexes were investigated under non‐isothermal condition. TG and DTG curves indicated that the complexes decompose in three to six steps. The photochemical behavior of the complexes depends on the substituted group on the aromatic aldehyde. A mechanism has been suggested to account for the recorded results.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
