河流州博多市收获大蕉中重金属和多环芳香族重金属的测定

Eze Chukwuebuka Gabriel, I. Chukwudozie, Arazu, H. OparajiEmeka
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引用次数: 0

摘要

分析了一株产自Gokana L.G.A Rivers州Bodo社区的大蕉的重金属和多环芳烃(PAHs)浓度。大蕉栽培用农业土壤的理化性质如下:pH值为5.7,而对照试验为7.4。试验和对照试验的土壤电导率分别为721和398。土壤矿物质含量:钾(6.88 mg/g)、磷(2.63 mg/g)、镁(12.42 mg/g)、氯离子(1021.21 mg/g)。土壤重金属分析表明,铜和铁的含量较高,而汞、砷和镉的含量均低于可检测限度。试验样品中Pb浓度相对较低,为24.12 mg/g,对照实验中为6.23 mg/g。土壤总氧化碳(TOC)含量为104.12 mg/g,总石油烃(TPH)含量为2567 mg/g。对照实验显示TOC和TPH浓度分别为42.85和1094 mg/g。对博多群落收获的车前草进行重金属分析,结果表明:铅(Pb)、铁(Fe)、铜(Cu)的含量依次为:Cu>Fe>Pb,而在对照试验中,铁(Fe)大于铜(Cu)。Bodo社区收获的车前草和对照试验收获的车前草中重金属汞、镉和砷均低于可检测限度。所有重金属的生物富集因子均<1。对照实验未检出苊、苊、蒽、芘和芴中的多环芳烃,而检测样品中仅检出了蒽。检测样品中萘、甲基萘、苊、苊、苯并(k)芴和芴的浓度相对高于芘和芴。对照实验中只记录了萘、甲基萘、芴和苯并(k)芴。试验样品中多环芳烃生物积累量最高的是苊(0.034 mg/g),对照实验中多环芳烃生物积累量最高的是芴(0.005 mg/g)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Estimation of Heavy Metals and Polycyclic Aromatic Heavy Metals in Harvested Plantains from Bodo, Rivers State
A Plantain harvested from Bodo community, Gokana L.G.A Rivers state were analyzed for heavy metals and Polycyclic Aromatic Hydrocarbons (PAHs) concentrations. Physicochemical properties of the agricultural soil used for the plantain cultivation showed the following: pH (5.7) while the control experiment was seen at 7.4. Soil conductivity of 721 and 398 were obtained for both the test and control experiments, respectively. Soil mineral contents: Potassium (6.88 mg/g), phosphorus (2.63 mg/g), Magnesium (12.42 mg/g), chloride ions (1021.21 mg/g). Heavy metal analysis of the soil showed a greater proportion of copper and iron in while Hg, As and Cd were below detectable limit in both tested samples. Pb was found relatively in lower concentrations of 24.12 mg/g in the test sample, 6.23 mg/g in the control experiment. Total Oxidizable Carbon Content (TOC) and Total Petroleum Hydrocarbon (TPH) content of the soil were observed at 104.12 and 2567 mg/g respectively in the tested sample. The control experiment showed TOC and TPH concentrations of 42.85 and 1094 mg/g. Heavy metal analysis of harvested plantain from Bodoh community showed the presence of the following: Lead (Pb), Iron (Fe) and Copper (Cu) in the following order: Cu>Fe>Pb in the test sample while in the control experiment, iron (Fe) was seen greater than copper (Cu). Heavy metals of mercury, cadmium and arsenic were below detectable limit at in both the harvested plantain from Bodo community and those of the control experiment, respectively. Bioaccumulation factor of all the heavy metals identified were <1. PAHs of Acenaphthalene, Acenaphthene, chrysene, pyrene and fluranthene were not detected in the control experiment while only chrysene was not detected in the test samples. Naphthalene,methyl naphthalene, acenaphthalene, acenaphthene, benzo (k) fluranthene and flourene were relatively high in concentration than pyrene and flouranthene in the test samples. Naphthalene, methylnaphthalene, flourene and benzo(k) flouranthene were only recorded in the control experiment. Acenaphthalene (0.034 mg/g) was seen as the highest PAHs in bioaccumulation in the test sample while flourene (0.005 mg/g) recorded the highest in the control experiment.
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