分子碘/水溶液NH4OAc:胺直接氧化合成腈的绿色反应体系

Q Chemistry

Journal of Advanced Oxidation Technologies Pub Date : 2017-01-01 DOI:10.1515/jaots-2016-0175

Yiming Ren, Shuo Jin

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引用次数: 0

摘要

摘要采用环境友好、价格低廉的试剂分子碘/水溶液NH4OAc，实现了一种绿色便捷的胺类合成腈的方法。水溶液NH4OAc作为绿色试剂比氨水更环保，因为气态氨容易从氨水中蒸发，而水溶液NH4OAc则不容易。并提出了反应的可能机理。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Molecular iodine/aqueous NH4OAc: a green reaction system for direct oxidative synthesis of nitriles from amines

Abstract A green and convenient approach for synthesis of nitriles from amines has been accomplished by using the environmentally friendly and inexpensive reagent molecular iodine/aqueous NH4OAc. The aqueous NH4OAc as a green reagent is more eco-friend than ammonia water, because of gaseous ammonia could be evaporated easily from ammonia water while aqueous NH4OAc is not. The possible mechanism of the present reaction was also proposed.

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来源期刊

Journal of Advanced Oxidation Technologies 化学-物理化学

CiteScore

0.88

自引率

0.00%

发文量

审稿时长

1 months

期刊介绍： The Journal of advanced oxidation technologies (AOTs) has been providing an international forum that accepts papers describing basic research and practical applications of these technologies. The Journal has been publishing articles in the form of critical reviews and research papers focused on the science and engineering of AOTs for water, air and soil treatment. Due to the enormous progress in the applications of various chemical and bio-oxidation and reduction processes, the scope of the Journal is now expanded to include submission in these areas so that high quality submission from industry would also be considered for publication. Specifically, the Journal is soliciting submission in the following areas (alphabetical order): -Advanced Oxidation Nanotechnologies -Bio-Oxidation and Reduction Processes -Catalytic Oxidation -Chemical Oxidation and Reduction Processes -Electrochemical Oxidation -Electrohydraulic Discharge, Cavitation & Sonolysis -Electron Beam & Gamma Irradiation -New Photocatalytic Materials and processes -Non-Thermal Plasma -Ozone-based AOTs -Photochemical Degradation Processes -Sub- and Supercritical Water Oxidation -TiO2 Photocatalytic Redox Processes -UV- and Solar Light-based AOTs -Water-Energy (and Food) Nexus of AOTs