{"title":"Sn (II)酞菁中金属原子动力学的温度依赖性[j];斯堡尔光谱","authors":"R. Herber","doi":"10.14494/JNRS2000.8.21","DOIUrl":null,"url":null,"abstract":"geometry. SnPc has been subjected to several 119Sn Mossbauer studies3 and the hyperfine parameters the isomer shift (IS) and quadrupole splitting (QS) have been reported2,4 at or near liquid nitrogen temperature. The focus of the present study is to relate the temperaturedependence of the recoil-free fraction, f, of the tin atom to the dynamics of the metal atom and to examine in detail the motional anisotropy of the metal center over a significant tem-","PeriodicalId":16569,"journal":{"name":"Journal of nuclear and radiochemical sciences","volume":"61 1","pages":"21-23"},"PeriodicalIF":0.0000,"publicationDate":"2007-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Metal Atom Dynamics in Sn (II) Phthalocyanin from Temperature-dependent 119Sn M^|^ouml;ssbauer Spectroscopy\",\"authors\":\"R. Herber\",\"doi\":\"10.14494/JNRS2000.8.21\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"geometry. SnPc has been subjected to several 119Sn Mossbauer studies3 and the hyperfine parameters the isomer shift (IS) and quadrupole splitting (QS) have been reported2,4 at or near liquid nitrogen temperature. The focus of the present study is to relate the temperaturedependence of the recoil-free fraction, f, of the tin atom to the dynamics of the metal atom and to examine in detail the motional anisotropy of the metal center over a significant tem-\",\"PeriodicalId\":16569,\"journal\":{\"name\":\"Journal of nuclear and radiochemical sciences\",\"volume\":\"61 1\",\"pages\":\"21-23\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2007-06-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of nuclear and radiochemical sciences\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.14494/JNRS2000.8.21\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of nuclear and radiochemical sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.14494/JNRS2000.8.21","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Metal Atom Dynamics in Sn (II) Phthalocyanin from Temperature-dependent 119Sn M^|^ouml;ssbauer Spectroscopy
geometry. SnPc has been subjected to several 119Sn Mossbauer studies3 and the hyperfine parameters the isomer shift (IS) and quadrupole splitting (QS) have been reported2,4 at or near liquid nitrogen temperature. The focus of the present study is to relate the temperaturedependence of the recoil-free fraction, f, of the tin atom to the dynamics of the metal atom and to examine in detail the motional anisotropy of the metal center over a significant tem-
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