利用外源细菌改善哥伦比亚卡拉卡拉油田生物修复过程

J. Molano
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引用次数: 0

摘要

哥伦比亚CEPSA开发了一种改进的生物修复技术;自2012年起在陆上Caracara油田实施。通过引入外源性细菌,优化了生物刺激和生物增强过程,效率(减少油脂)接近90%。该技术的性能超过了其他已发表的方法,因为它已成功地用于生物处理含有碳氢化合物的土壤和流体,其脂肪和油的浓度高达20±2 wt%,相当于200,000±20,000 ppm (mg碳/kg土壤)。之前的研究表明,只有油脂浓度低于该水平的一半左右的含油污泥才能进行生物修复,以达到路易斯安那议定书29-B第三章规定的接近1wt %的合规标准,并被普遍采用为石油行业规范。这是一种“移地”工艺,因为尽管在现场应用,污泥在批量生物处理之前首先被收集和储存。该技术最适用于沥青质和树脂含量不高的含油污泥:由于沥青质结构复杂,且对细菌产生的酶侵蚀具有抗性,因此微生物无法对其进行生物降解。我们成功的现场试验已经扩展到工业规模,并在六年的时间里有效地处理了大约12,000立方米的污泥池的环境责任,这些污泥池是CEPSA在Caracara油田获得权益时继承的。作业继续进行,处理正在产生的含油废物,与与外部生物修复服务提供商签约的处理和运输成本相比,估计可节省54%的成本。我们已经制定了简单的标准来筛选我们的工艺中含油污泥的适用性,该工艺简单,易于实施且具有成本效益,因为它依赖于从现场现成的废物中产生的细菌,而不需要任何成本。应适用于具有类似环境条件的其他领域。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Use of Exogenous Bacteria to Improve the Bioremediation Process in the Caracara Field Colombia
CEPSA Colombia developed an improved technique for bioremediation; implemented since 2012 in the onshore Caracara field. This optimizes the processes of biostimulation and bioaugmentation by introducing exogenous bacteria, with efficiency (reduction of grease and oil) close to 90%. The technique exceeds the performance of other published methods, as it has been used successfully for the biotreatment of soils and fluids impregnated with hydrocarbons at concentrations of fats and oil of up to 20 ± 2 wt%, equivalent to 200,000 ± 20,000 ppm (mg carbon/kg soil). Previous studies have suggested that oily sludges only with concentrations of fats and oils below approximately half that level can be bioremediated to achieve a compliance criterion standard close to 1 wt% as established in Chapter III of Louisiana Protocol 29-B and commonly adopted as an oil industry norm. It is an ‘ex situ’ process since although applied at the field location the sludge is first collected and stored prior to batch biotreatment. The technique is most applicable to oily sludges that do not have an excessive asphaltene and resins content: asphaltenes are not biodegradable by microorganisms, given their structural complexity and resistance to the enzymatic attack produced by bacteria. Our successful field pilot has been expanded to an industrial scale and has over a six-year period effectively treated the environmental liability of sludge ponds of approximately 12,000 m3 inherited when CEPSA assumed its interest in the Caracara field. Operations continue, treating ongoing generation of oily waste at an estimated cost saving of 54% relative to the treatment and transport costs of contracting an external bioremediation service provider. We have developed simple criteria to screen the suitability of oily sludges for our process, which is simple, easy to implement and cost-effective, as it relies on bacteria generated from waste products readily available in the field at no cost. It should be applicable to other fields with similar environmental conditions.
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