t = 328.15 k时硝酸钙-硝酸铵熔体中溴化钴络合物形成的分光光度法研究。含水量的影响

M. Vraneš, J. Panić, S. Papović, Teodora Teona Borović, A. Tot, Nikolet Baganj, S. Gadžurić
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摘要

本文研究了0.3Ca(NO3)2 - 0.7NH4NO3 - H2O组成的硝酸钴(II)和溴化物配合物在400-800 nm波长范围内,T = 328.15 K,大气压P = 101.3 kPa的吸收光谱。在不同含水量的溶液中记录光谱(R = H2O/盐摩尔比;R = 1.0, 1.2, 1.6)。随着水含量的增加,吸收最大值的蓝移(R)表明水分子和硝酸盐离子同时配位。光谱分析表明:形成了[Co(NO3)4(H2O)2]2−、[Co(NO3)2Br2]2−和[CoBr4]2−配合物。在T = 328.15 K时计算了这些配合物的总稳定常数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
SPECTROPHOTOMETRIC INVESTIGATION OF COBALT BROMIDE COMPLEX FORMATION IN AQUEOUS CALCIUM NITRATE– AMMONIUM NITRATE MELTS AT T = 328.15 K. INFLUENCE OF WATER CONTENT
In this work, the absorption spectra of cobalt(II) nitrate and bromide complexes in the composition 0.3Ca(NO3)2 – 0.7NH4NO3 – H2O have been investigated in the 400-800 nm range of wavelength at T = 328.15 K and atmospheric pressure P = 101.3 kPa. Spectra were recorded in solutions with variable water content (R = H2O/salt mole ratio; R = 1.0, 1.2 and 1.6). The blue shift of the absorption maximum with the water content increase (R) suggest simultaneous coordination by water molecules and nitrate ions. From an analysis of the spectra, it can be concluded that the following: [Co(NO3)4(H2O)2]2−, [Co(NO3)2Br2]2− and [CoBr4]2− complexes were formed. The overall stability constants of these complexes species spectra were calculated at T = 328.15 K.
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