载体对OMS-2气相氧化甲苯催化活性影响的研究

Trung Thanh Nguyen, Ngoc Hanh Nguyen, T. N. Thi, Tri Thich Le, Phuoc Toan Phan, N. Nguyen
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引用次数: 0

摘要

本研究在连续固定床反应器中将甲苯等芳烃化合物完全氧化为二氧化碳和水。采用回流法合成的OMS-2材料作为催化剂。为了降低催化剂的成本,采用了多种载体材料来支撑OMS-2催化剂。研究了膨润土、高岭石和氧化铝等载体及其含量对OMS-2氧化甲苯催化活性的影响。载体中,铝硅比为1:2的膨润土为最佳材料,最低温度为260℃,甲苯转化率达到100%。因此,20%OMS-2/膨润土可以作为一种高效、低成本的催化剂用于甲苯和其他有机化合物的气相催化氧化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Study on the Effect of Support on the Catalytic Activity of OMS-2 for Oxidation of Toluene in Gas Phase
In this study, the complete oxidation of an aromatic hydrocarbon compound such as toluene into carbon dioxide and water was carried out in a continuous fixed bed reactor. OMS-2 material synthesized by the refluxing method was used as the catalyst. To reduce the cost of the catalyst, various support materials were employed for supporting the OMS-2 catalyst. The effects of supports (i.e., bentonite, kaolinite, and alumina) and their contents on the catalytic activity of OMS-2 for the oxidation of toluene were investigated. Among the supports, bentonite with Al:Si ratio of 1:2 was the best material with the lowest temperature that reached 100% of toluene conversion at 260 oC. Therefore, 20%OMS-2/bentonite could be a suitable catalyst with high efficiency but low cost for catalytic oxidation of toluene and other organic compounds in the gas phase.
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