{"title":"傅里叶变换拉曼光谱在聚ε-己内酰胺链构象测定中的应用","authors":"P. Schmidt, P.J. Hendra","doi":"10.1016/0584-8539(94)80211-4","DOIUrl":null,"url":null,"abstract":"<div><p>The Fourier-transform Raman spectra of various structural forms of poly(ε-caprolactam) have been obtained and the Raman bands characterizing planar and nonplanar conformation of the ε-caprolactam units have been defined. These bands have been used for the investigation of the conformational composition of ε-caprolactam sequences in several ε-caprolactam-butadiene block copolymers.</p></div>","PeriodicalId":82782,"journal":{"name":"Spectrochimica acta. Part A: Molecular spectroscopy","volume":"50 11","pages":"Pages 1999-2004"},"PeriodicalIF":0.0000,"publicationDate":"1994-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0584-8539(94)80211-4","citationCount":"11","resultStr":"{\"title\":\"The application of Fourier-transform Raman spectroscopy to the determination of conformation in poly(ε-caprolactam) chains\",\"authors\":\"P. Schmidt, P.J. Hendra\",\"doi\":\"10.1016/0584-8539(94)80211-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Fourier-transform Raman spectra of various structural forms of poly(ε-caprolactam) have been obtained and the Raman bands characterizing planar and nonplanar conformation of the ε-caprolactam units have been defined. These bands have been used for the investigation of the conformational composition of ε-caprolactam sequences in several ε-caprolactam-butadiene block copolymers.</p></div>\",\"PeriodicalId\":82782,\"journal\":{\"name\":\"Spectrochimica acta. Part A: Molecular spectroscopy\",\"volume\":\"50 11\",\"pages\":\"Pages 1999-2004\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0584-8539(94)80211-4\",\"citationCount\":\"11\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica acta. Part A: Molecular spectroscopy\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0584853994802114\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica acta. Part A: Molecular spectroscopy","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0584853994802114","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The application of Fourier-transform Raman spectroscopy to the determination of conformation in poly(ε-caprolactam) chains
The Fourier-transform Raman spectra of various structural forms of poly(ε-caprolactam) have been obtained and the Raman bands characterizing planar and nonplanar conformation of the ε-caprolactam units have been defined. These bands have been used for the investigation of the conformational composition of ε-caprolactam sequences in several ε-caprolactam-butadiene block copolymers.
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