基于稀土元素锆酸盐的陶瓷材料火花等离子烧结

S. Oglezneva, S. Porozova, M. Kachenyuk, V. Kul’met’eva, A. Smetkin
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引用次数: 0

摘要

采用反向化学沉淀法合成稀土锆酸盐、La2Zr2O7和ZrO2-8Y2O3粉体,并在此基础上采用火花等离子烧结法制备陶瓷材料。研究了放电等离子烧结固结过程中陶瓷相组成的形成。稀土锆酸盐基陶瓷在400℃时的导热系数为1.79 W/(m·K),低于La2Zr2O7 - 2.06 W/(m·K)和ZrO2-8Y2O3 - 2.4 W/(m·K)。结果表明,使用稀土氧化物精矿可以获得在1200℃以上温度下具有热稳定性的热屏蔽涂层陶瓷层。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Spark plasma sintering of ceramic materials based on zirconates of rare-earth elements
Powders of rare-earth zirconates, La2Zr2O7 and ZrO2‒8Y2O3 were synthesized by reverse chemical precipitation to obtain ceramic materials on their basis by spark plasma sintering. The formation of the phase composition of ceramics during consolidation by spark plasma sintering has been studied. The thermal conductivity of ceramics based on REE zirconates at 400 °C is 1,79 W/(m·K), which is less than that of La2Zr2O7 ― 2,06 W/(m·K) and ZrO2‒8Y2O3 ― 2,4 W/(m·K). It is shown that the use of REE oxide concentrate is promising for obtaining a ceramic layer of heat-shielding coatings with thermal stability at temperatures above 1200 °C.
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