聚合物和层状矿物的纳米复合材料

H.R. Fischer, L.H. Gielgens, T.P.M. Koster
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引用次数: 194

摘要

将天然或人工合成的层状矿物(如粘土)与聚合物基体材料结合,在两者之间加入特殊的增容剂,制备出复合材料。应用嵌段共聚物或接枝共聚物,结合与有机聚合物相同和/或完全可混溶的聚合物的一部分和与天然矿物相容的另一部分,作为相容剂。相容剂第一部分之间的相互作用优选为离子相互作用或通过氢键的相互作用。这种相互作用导致矿物分离成单片和/或含有约2-10片的小团簇,随后这些团簇均匀地结合到聚合物基体材料中。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Nanocomposites from polymers and layered minerals

Composites consisting of polymer matrix materials and natural or synthetic layered minerals e.g. clays were prepared by using special compatibilizing agents between these two intrinsically non-miscible components. Block or graft copolymers combining one part of the polymer that is identically and/or completely miscible with the organic polymer and another part that is compatible with the natural mineral are applied to act as compatibilizer. The interaction between the first part of the compatibilizer is preferentially an ionic interaction or an interaction via hydrogen bonds. This interaction leads to a separation of the mineral into single sheets and/or small clusters containing approximately 2–10 sheets and a subsequent homogeneous incorporation of these clusters into the polymer matrix material.

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