{"title":"电子衍射测定(CH3) 3X-CC-Y (XSi, Ge, YH, Cl)型分子结构","authors":"W. Zeil, J. Haase, M. Dakkouri","doi":"10.1039/DF9694700149","DOIUrl":null,"url":null,"abstract":"The structure of the molecules (CH3)3Si—CC—H, (CH3)3Si—CC—Cl and (CH3)3Ge—CC—Cl as gases have been determined using electron diffraction. The lengths of the CC bond show no significant differences from the corresponding bond length in carbon compounds. We conclude therefore that the length of the CC bond is insensitive to π-electron delocalization.","PeriodicalId":11262,"journal":{"name":"Discussions of The Faraday Society","volume":"14 1","pages":"149-156"},"PeriodicalIF":0.0000,"publicationDate":"1969-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"30","resultStr":"{\"title\":\"Structure of molecules of type (CH3)3X—CC—Y (XSi, Ge, YH, Cl) determined by electron diffraction\",\"authors\":\"W. Zeil, J. Haase, M. Dakkouri\",\"doi\":\"10.1039/DF9694700149\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The structure of the molecules (CH3)3Si—CC—H, (CH3)3Si—CC—Cl and (CH3)3Ge—CC—Cl as gases have been determined using electron diffraction. The lengths of the CC bond show no significant differences from the corresponding bond length in carbon compounds. We conclude therefore that the length of the CC bond is insensitive to π-electron delocalization.\",\"PeriodicalId\":11262,\"journal\":{\"name\":\"Discussions of The Faraday Society\",\"volume\":\"14 1\",\"pages\":\"149-156\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1969-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"30\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Discussions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/DF9694700149\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Discussions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/DF9694700149","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Structure of molecules of type (CH3)3X—CC—Y (XSi, Ge, YH, Cl) determined by electron diffraction
The structure of the molecules (CH3)3Si—CC—H, (CH3)3Si—CC—Cl and (CH3)3Ge—CC—Cl as gases have been determined using electron diffraction. The lengths of the CC bond show no significant differences from the corresponding bond length in carbon compounds. We conclude therefore that the length of the CC bond is insensitive to π-electron delocalization.
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