{"title":"烷基芳烃的可逆异构化","authors":"A. Osman, M. Badr, A. Abdel-rahman","doi":"10.1039/J39710002264","DOIUrl":null,"url":null,"abstract":"The isomerisation of α- and β-benzyl- and substituted-benzyl-naphthalenes catalysed by anhydrous aluminium chloride or toluene-p-sulphonic acid has been studied.Halogen-substituted-benzylnaphthalenes failed to isomerise whilst p-methyl- and p-methoxy-benzylnaphthalenes, isomerise more readily than benzylnaphthalene. The isomerisation is reversible, and aluminium chloride is more effective than toluene-p-sulphonic acid.","PeriodicalId":17245,"journal":{"name":"Journal of The Chemical Society C: Organic","volume":"8 1","pages":"2264-2265"},"PeriodicalIF":0.0000,"publicationDate":"2007-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Reversible isomerisation of alkyl aromatics\",\"authors\":\"A. Osman, M. Badr, A. Abdel-rahman\",\"doi\":\"10.1039/J39710002264\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The isomerisation of α- and β-benzyl- and substituted-benzyl-naphthalenes catalysed by anhydrous aluminium chloride or toluene-p-sulphonic acid has been studied.Halogen-substituted-benzylnaphthalenes failed to isomerise whilst p-methyl- and p-methoxy-benzylnaphthalenes, isomerise more readily than benzylnaphthalene. The isomerisation is reversible, and aluminium chloride is more effective than toluene-p-sulphonic acid.\",\"PeriodicalId\":17245,\"journal\":{\"name\":\"Journal of The Chemical Society C: Organic\",\"volume\":\"8 1\",\"pages\":\"2264-2265\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2007-04-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society C: Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J39710002264\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society C: Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J39710002264","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The isomerisation of α- and β-benzyl- and substituted-benzyl-naphthalenes catalysed by anhydrous aluminium chloride or toluene-p-sulphonic acid has been studied.Halogen-substituted-benzylnaphthalenes failed to isomerise whilst p-methyl- and p-methoxy-benzylnaphthalenes, isomerise more readily than benzylnaphthalene. The isomerisation is reversible, and aluminium chloride is more effective than toluene-p-sulphonic acid.
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