The Role of CO2 in Carbonate Acidizing at the Field Scale – A Multi-Phase Perspective

Most lab-scale acidizing experiments are performed in core samples with 100% water saturation conditions and at pore pressures around 1100 psi. However, this is seldom the case on the field, where different saturation conditions exist with high temperature and pressure conditions. Carbon-di-Oxide (CO2), a by-product evolved during the acidizing process, is long thought to behave inertly during the acidizing process. Recent investigations reveal that the presence of CO2 dynamically changes the behavior of wormhole patterns and acid efficiency. A compositional simulation technique was adopted to understand the process thoroughly. A validated compositional numerical model capable of replicating acidizing experiments at the core-scale level, in fully aqueous environments described in published literature was utilized in this study. The numerical model was extended to a three-phase environment and applied at the field scale level to monitor and evaluate the impacts of evolved CO2 during the carbonate acidizing processes. Lessons learned from the lab-scale were tested at the field-scale scenario via a numerical model with radial coordinates. Contrary to popular belief, high pore pressures of 1,000 psi and above are not sufficient to keep all the evolved CO2 in solution. The presence of CO2 as a separate phase hinders acid efficiency. The reach or extent of the evolved CO2 is shown to exist only near the damage zone and seldom penetrates the reservoir matrix. Based on the field scale model's predictions, this study warrants conducting acidizing experiments at the laboratory level, at precisely similar pressure, temperature, and salinity conditions faced in the near-wellbore region, and urges the application of compositional modeling techniques to account for CO2 evolution, while studying and predicting matrix acidizing jobs.