Cu(II)掺杂TiO2光降解Remazol Black B的研究

M. Momen, M. Rahman, H. Begum, M. Hossain
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引用次数: 0

摘要

本研究采用沉淀法制备了Cu(II)掺杂TiO2。沉淀物在300℃下煅烧2小时。采用扫描电镜(SEM)、能谱仪(EDX)和x射线衍射仪(XRD)对所制备的掺杂催化剂进行了表征。SEM图像显示,掺杂催化剂的形貌与TiO2不同。EDX元素分析表明制备的样品中存在Cu、Ti和O原子。XRD分析证实TiO2以锐钛矿形式存在,由于部分间隙位存在Cu(II), TiO2峰位几乎没有畸变。研究了雷马唑黑B (RBB)在不同光源和不同条件下的光降解。Cu(II)掺杂TiO2的催化效率在一定剂量后随光催化剂用量的增加而降低。在紫外光照射下,pH为3.0的条件下降解效果最佳。在此实验条件下,Cu(II)掺杂TiO2对RBB的降解率为98.8%,而未掺杂TiO2对RBB的降解率仅为80.0%。达卡大学学报,70(1):64-69,2022 (1)
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Cu(II) Doped TiO2 for Photodegradation of Remazol Black B in Aqueous Solution
In the present investigation, Cu(II) doped TiO2 was prepared by a precipitation method. The precipitate was calcined at 300 ºC for2 hours. The prepared doped catalyst was characterized by scanning electron microscope (SEM), energy dispersive X-ray (EDX)spectroscopy and X-ray diffractometry (XRD). SEM images revealed that the morphology of the doped catalyst was different fromthat of TiO2. Elemental analysis was accomplished by EDX that indicated the presence of Cu, Ti and O atoms in the prepared sample.XRD analysis confirmed that TiO2 was present as anatase with almost no distortion in peak position due to the presence of Cu(II)in some interstitial sites. Photodegradation of remazol black B (RBB) was carried out at different experimental conditions underdifferent light sources. The catalytic efficiency of Cu(II) doped TiO2 increased up to a certain dosage then reduced with a furtherincrease in the amount of photocatalyst. The optimum conditions for degradation was found at pH 3.0 under UV light. Under theseexperimental conditions, Cu(II) doped TiO2 degraded 98.8% of RBB, on the other hand, undoped TiO2 degraded only 80.0% of RBB. Dhaka Univ. J. Sci. 70(1): 64-69, 2022 (January)
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