{"title":"氧化铁卟啉偏二乙烯-羰基配合物的替代电子和分子结构配方","authors":"Harold M. Goff ∗, Martin A. Phillippi","doi":"10.1016/0020-1650(81)80009-8","DOIUrl":null,"url":null,"abstract":"<div><p>Oxidation of iron porphyrin vinylidene complexes yields products previously formulated as having an important iron(IV) porphyrin π-cation radical resonance form. Reconsideration of literature results and analogous cobalt porphyrin reactions leads to the conclusion that pyrrole nitrogen alkylation occurs and that the likely electronic structure is that of an intermediate-spin (S = <span><math><mtext>3</mtext><mtext>2</mtext></math></span>) iron(III) porphyrin.</p></div>","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80009-8","citationCount":"3","resultStr":"{\"title\":\"Alternate electronic and molecular structural formulations for oxidized iron porphyrin vinylidene-carbene complexes\",\"authors\":\"Harold M. Goff ∗, Martin A. Phillippi\",\"doi\":\"10.1016/0020-1650(81)80009-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Oxidation of iron porphyrin vinylidene complexes yields products previously formulated as having an important iron(IV) porphyrin π-cation radical resonance form. Reconsideration of literature results and analogous cobalt porphyrin reactions leads to the conclusion that pyrrole nitrogen alkylation occurs and that the likely electronic structure is that of an intermediate-spin (S = <span><math><mtext>3</mtext><mtext>2</mtext></math></span>) iron(III) porphyrin.</p></div>\",\"PeriodicalId\":13630,\"journal\":{\"name\":\"Inorganic and Nuclear Chemistry Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-1650(81)80009-8\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic and Nuclear Chemistry Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020165081800098\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic and Nuclear Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020165081800098","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Alternate electronic and molecular structural formulations for oxidized iron porphyrin vinylidene-carbene complexes
Oxidation of iron porphyrin vinylidene complexes yields products previously formulated as having an important iron(IV) porphyrin π-cation radical resonance form. Reconsideration of literature results and analogous cobalt porphyrin reactions leads to the conclusion that pyrrole nitrogen alkylation occurs and that the likely electronic structure is that of an intermediate-spin (S = ) iron(III) porphyrin.
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