{"title":"激光闪光光解孟加拉玫瑰与铁芳烃配合物相互作用的研究","authors":"D. Burget, J. Fouassier","doi":"10.1039/A801981I","DOIUrl":null,"url":null,"abstract":"Interaction between Rose Bengal (RB) and an iron arene complex [Irg(+)] was studied by steady state and laser flash photolysis experiments. The contribution of static fluorescence quenching is evidenced by time resolved fluorescence experiments and can be explained by the occurrence of a ground state complex between RB and Irg(+). After light absorption by RB, the singlet state of RB is intercepted within the RB/Irg(+) pair, leading to semi-oxidised RB and a 19e iron arene complex.","PeriodicalId":17286,"journal":{"name":"Journal of the Chemical Society, Faraday Transactions","volume":"1 1","pages":"1849-1854"},"PeriodicalIF":0.0000,"publicationDate":"1998-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"28","resultStr":"{\"title\":\"Laser flash photolysis studies of the interaction of Rose Bengal with an iron arene complex\",\"authors\":\"D. Burget, J. Fouassier\",\"doi\":\"10.1039/A801981I\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Interaction between Rose Bengal (RB) and an iron arene complex [Irg(+)] was studied by steady state and laser flash photolysis experiments. The contribution of static fluorescence quenching is evidenced by time resolved fluorescence experiments and can be explained by the occurrence of a ground state complex between RB and Irg(+). After light absorption by RB, the singlet state of RB is intercepted within the RB/Irg(+) pair, leading to semi-oxidised RB and a 19e iron arene complex.\",\"PeriodicalId\":17286,\"journal\":{\"name\":\"Journal of the Chemical Society, Faraday Transactions\",\"volume\":\"1 1\",\"pages\":\"1849-1854\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"28\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Chemical Society, Faraday Transactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/A801981I\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Chemical Society, Faraday Transactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/A801981I","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Laser flash photolysis studies of the interaction of Rose Bengal with an iron arene complex
Interaction between Rose Bengal (RB) and an iron arene complex [Irg(+)] was studied by steady state and laser flash photolysis experiments. The contribution of static fluorescence quenching is evidenced by time resolved fluorescence experiments and can be explained by the occurrence of a ground state complex between RB and Irg(+). After light absorption by RB, the singlet state of RB is intercepted within the RB/Irg(+) pair, leading to semi-oxidised RB and a 19e iron arene complex.
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