{"title":"膦配位铑配合物对2-丙醇脱氢的催化作用","authors":"Toshiaki Matsubara , Yasukazu Saito","doi":"10.1016/0304-5102(94)00033-6","DOIUrl":null,"url":null,"abstract":"<div><p>The Wilkinson complex RhCl (PPh<sub>3</sub>)<sub>3</sub>, which is inactive for 2-propanol dehydrogenation, exhibited its catalytic activity by adding Et<sub>3</sub>N, or by using a hydride complex, instead of chloride, for ketone hydrogenation as well. The elemental steps of the proposed dehydrogenation cycle was investigated with EHMO method.</p></div>","PeriodicalId":16567,"journal":{"name":"分子催化","volume":"92 1","pages":"Pages 1-8"},"PeriodicalIF":0.0000,"publicationDate":"1994-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0304-5102(94)00033-6","citationCount":"19","resultStr":"{\"title\":\"Catalysis of phosphine-coordinated rhodium(I) complexes for 2-propanol dehydrogenation\",\"authors\":\"Toshiaki Matsubara , Yasukazu Saito\",\"doi\":\"10.1016/0304-5102(94)00033-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Wilkinson complex RhCl (PPh<sub>3</sub>)<sub>3</sub>, which is inactive for 2-propanol dehydrogenation, exhibited its catalytic activity by adding Et<sub>3</sub>N, or by using a hydride complex, instead of chloride, for ketone hydrogenation as well. The elemental steps of the proposed dehydrogenation cycle was investigated with EHMO method.</p></div>\",\"PeriodicalId\":16567,\"journal\":{\"name\":\"分子催化\",\"volume\":\"92 1\",\"pages\":\"Pages 1-8\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-08-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0304-5102(94)00033-6\",\"citationCount\":\"19\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"分子催化\",\"FirstCategoryId\":\"1089\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0304510294000336\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"Chemical Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"分子催化","FirstCategoryId":"1089","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0304510294000336","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Chemical Engineering","Score":null,"Total":0}
Catalysis of phosphine-coordinated rhodium(I) complexes for 2-propanol dehydrogenation
The Wilkinson complex RhCl (PPh3)3, which is inactive for 2-propanol dehydrogenation, exhibited its catalytic activity by adding Et3N, or by using a hydride complex, instead of chloride, for ketone hydrogenation as well. The elemental steps of the proposed dehydrogenation cycle was investigated with EHMO method.
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