电催化析氧聚合物配合物

H. Shinohara, H. Nishide
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引用次数: 0

摘要

电催化水氧化析氧技术从可持续发展的角度得到了广泛的研究。然而,使用有机聚合物作为该反应的催化剂层仍未开发。本文讨论了π共轭聚合物作为电化学催化剂修饰阳极集流器用于水氧化的前提条件、特点和优点,并引用了文献中的一些例子。在第3节中,我们展示了我们的最新成果,利用亲水聚(羟基甲基丙烯酸乙酯)平台支持的聚(乙烯二氧噻吩)和植酸的有机聚合物配合物,通过阳极水氧化有效地产生氧气。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Polymer Complexes for Electrocatalytic Oxygen Evolution
Electrocatalytic water oxidation for oxygen gas evolution has been widely studied from the perspective of sustainable technology. However, the use of organic polymers as catalyst layers for this reaction remains un-developed. We discuss, here, the prerequisites, characteristics, and advantages of π-conjugated polymers as electrochemical catalysts to modify anodic current collectors for water oxidation, including some examples by citing the previous works in literature. In section 3, we present our latest results, the use of an organic pol-ymer complex of poly(ethylenedioxythiophene) and phytic acid supported by a hydrophilic poly(hydroxy-ethyl methacrylate) platform, which efficiently generates oxygen gas through anodic water oxidation.
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